Five-Coordinate Sulfur in a Polymeric Copper(I) Thiolate Complex

Angewandte Chemie (International Edition in English)

Volumn 36, Issue 3, 1997, Pages 251-253

  Parish, Richard V ^a   Salehi, Zahra ^a   Pritchard, Robin G ^a  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

Author keywords

Cage compounds; Clusters; Coordination modes; Copper; S ligands

Indexed keywords

EID: 0030970859     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199702511     Document Type: Article

References (12)

1. I. G. Dance, Polyhedron 1986, 5, 1037.
2. V. Vorisch, P. Kroneck, P. Hemmerick, J. Am. Chem. Soc. 1976, 98, 2821.
3. 3C1 (20 mmol) in water (350 mL) was added gradually with stirring CuCl (5 mmol). After standing in air for 10 days a large quantity of colorless crystals formed.
4. Kα, (λ = 0.71069 Å); ω/2θ scan; T = 293 K; of 4450 reflections measured, 4317 were unique and 1429 were used; σ > 3σ(I); Lorentzian polarization/absorption (transmission 0.81-1.0; direct methods, SHELX86; full-matrix least-squares refinement based on F, TEXSAN, 235 parameters, hydrogen atoms included in calculated positions; R(wR) = 0.053 (0.062); residual electron density 1.34,-1.13 eÅ. The crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-179-104. Copies of the data may be obtained free of charge on application to the Director of the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK (fax: Int. code +(1223)336-033; email: deposit@chemcrys.cam.ac.uk).
5. in the structure diagrams, ′ signifies -x, -y, -z; i signifies -x, y, -z - 1/2, j signifies x, -y, 1/2+z; k signifies -x, 1 -y, -z.
6. R. K. Chadha, R. Kumar, D. G. Tuck, Polyhedron 1988, 7, 1121; E. Block, M. Gernon, H. Kang, S. Liu, J. Zubieta, Inorg. Chem. 1989, 28, 1263; A. L. Rheingold, S. Munavalli, D. I. Rossman, C. P. Ferguson, ibid. 1994, 33. 1723; I. G. Dance, L. J. Fitzpatrick,. D. C. Craig, M. L. Scudder, ibid. 1989, 28, 1853; M. Baumgartner, H. Schmalle, E. Dubler, Poyhedron 1990, 9, 1155; T. Okamura, N. Ueyama, A. Nakamura, E. W. Ainscough, A. M. Brodie, J. M. Waters, J. Chem. Soc. Chem Commun. 1993, 1658
7. R. K. Chadha, R. Kumar, D. G. Tuck, Polyhedron 1988, 7, 1121; E. Block, M. Gernon, H. Kang, S. Liu, J. Zubieta, Inorg. Chem. 1989, 28, 1263; A. L. Rheingold, S. Munavalli, D. I. Rossman, C. P. Ferguson, ibid. 1994, 33. 1723; I. G. Dance, L. J. Fitzpatrick,. D. C. Craig, M. L. Scudder, ibid. 1989, 28, 1853; M. Baumgartner, H. Schmalle, E. Dubler, Poyhedron 1990, 9, 1155; T. Okamura, N. Ueyama, A. Nakamura, E. W. Ainscough, A. M. Brodie, J. M. Waters, J. Chem. Soc. Chem Commun. 1993, 1658
8. R. K. Chadha, R. Kumar, D. G. Tuck, Polyhedron 1988, 7, 1121; E. Block, M. Gernon, H. Kang, S. Liu, J. Zubieta, Inorg. Chem. 1989, 28, 1263; A. L. Rheingold, S. Munavalli, D. I. Rossman, C. P. Ferguson, ibid. 1994, 33. 1723; I. G. Dance, L. J. Fitzpatrick,. D. C. Craig, M. L. Scudder, ibid. 1989, 28, 1853; M. Baumgartner, H. Schmalle, E. Dubler, Poyhedron 1990, 9, 1155; T. Okamura, N. Ueyama, A. Nakamura, E. W. Ainscough, A. M. Brodie, J. M. Waters, J. Chem. Soc. Chem Commun. 1993, 1658
9. R. K. Chadha, R. Kumar, D. G. Tuck, Polyhedron 1988, 7, 1121; E. Block, M. Gernon, H. Kang, S. Liu, J. Zubieta, Inorg. Chem. 1989, 28, 1263; A. L. Rheingold, S. Munavalli, D. I. Rossman, C. P. Ferguson, ibid. 1994, 33. 1723; I. G. Dance, L. J. Fitzpatrick,. D. C. Craig, M. L. Scudder, ibid. 1989, 28, 1853; M. Baumgartner, H. Schmalle, E. Dubler, Poyhedron 1990, 9, 1155; T. Okamura, N. Ueyama, A. Nakamura, E. W. Ainscough, A. M. Brodie, J. M. Waters, J. Chem. Soc. Chem Commun. 1993, 1658
10. R. K. Chadha, R. Kumar, D. G. Tuck, Polyhedron 1988, 7, 1121; E. Block, M. Gernon, H. Kang, S. Liu, J. Zubieta, Inorg. Chem. 1989, 28, 1263; A. L. Rheingold, S. Munavalli, D. I. Rossman, C. P. Ferguson, ibid. 1994, 33. 1723; I. G. Dance, L. J. Fitzpatrick,. D. C. Craig, M. L. Scudder, ibid. 1989, 28, 1853; M. Baumgartner, H. Schmalle, E. Dubler, Poyhedron 1990, 9, 1155; T. Okamura, N. Ueyama, A. Nakamura, E. W. Ainscough, A. M. Brodie, J. M. Waters, J. Chem. Soc. Chem Commun. 1993, 1658
11. R. K. Chadha, R. Kumar, D. G. Tuck, Polyhedron 1988, 7, 1121; E. Block, M. Gernon, H. Kang, S. Liu, J. Zubieta, Inorg. Chem. 1989, 28, 1263; A. L. Rheingold, S. Munavalli, D. I. Rossman, C. P. Ferguson, ibid. 1994, 33. 1723; I. G. Dance, L. J. Fitzpatrick,. D. C. Craig, M. L. Scudder, ibid. 1989, 28, 1853; M. Baumgartner, H. Schmalle, E. Dubler, Poyhedron 1990, 9, 1155; T. Okamura, N. Ueyama, A. Nakamura, E. W. Ainscough, A. M. Brodie, J. M. Waters, J. Chem. Soc. Chem Commun. 1993, 1658
12. G. W. Adamson, N. A. Bell, H. M. M. Shearer, Acta Crystallogr. Sect B 1982, 38, 462.