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Volumn 119, Issue 37, 1997, Pages 8732-8733

Determination of the exchange-coupling constant of an Fe3+-Fe3+ pair in a cubane-type iron-sulfur cluster

Author keywords

[No Author keywords available]

Indexed keywords

FERRIC ION; IRON DERIVATIVE; SULFUR DERIVATIVE;

EID: 0030961032     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja971171f     Document Type: Article
Times cited : (25)

References (33)
  • 17
    • 85088809964 scopus 로고    scopus 로고
    • note
    • -1) point to some fundamental problems which have to be resolved (requiring perhaps amending the spin Hamiltonian with terms describing interactions such as anisotropic exchange).
  • 23
    • 33646957659 scopus 로고    scopus 로고
    • note
    • 22 then yielded accurate values for the sample magnetization. For the studies performed here, the MPMS Quantum Design SQUID susceptometer was calibrated with a palladium standard.
  • 25
    • 33646957897 scopus 로고    scopus 로고
    • note
    • 2 mol for 2.
  • 27
    • 85088810438 scopus 로고    scopus 로고
    • note
    • 2+ sites are strictly diamagnetic up to T = 300 K. Suitable model complexes for testing this assumption are not available. However, the presence of strong ligands at the two octahedral cluster sites suggests a low-spin (S = 0) ground state and excited states which are thermally not accessible at the temperatures of the measurements.
  • 31
    • 85088810074 scopus 로고    scopus 로고
    • note
    • -1.30


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.