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Volumn 36, Issue 4, 1997, Pages 378-381

Unexpected Intramolecular Reactions of Intermediate Phosphacarbonyl Ylide Tungsten Complexes

Author keywords

Carbonyl compounds; Cycloadditions; Phosphorus; Tungsten; Ylides

Indexed keywords


EID: 0030956693     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199703781     Document Type: Article
Times cited : (61)

References (37)
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    • For the first synthesis of an oxaphosphirane tungsten complex by epoxidation of a methylenephosphane tungsten complex, see S. Bauer, A. Marinetti, L. Ricard, F. Mathey, Angew. Chem. 1990, 102, 1188; Angew. Chem. Int. Ed. Engl. 1990, 29, 1166.
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    • For the first synthesis of an oxaphosphirane tungsten complex by epoxidation of a methylenephosphane tungsten complex, see S. Bauer, A. Marinetti, L. Ricard, F. Mathey, Angew. Chem. 1990, 102, 1188; Angew. Chem. Int. Ed. Engl. 1990, 29, 1166.
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    • Nucleophilic, terminal phosphanediyl-metal complexes react with aldehydes to form methylenephosphanes: see a) C. C. Cummins, R. R. Schrock, W. M. Davis, Angew. Chem. 1993, 105, 758; Angew. Chem. Int. Ed. Engl. 1993, 32, 756;
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    • Nucleophilic, terminal phosphanediyl-metal complexes react with aldehydes to form methylenephosphanes: see a) C. C. Cummins, R. R. Schrock, W. M. Davis, Angew. Chem. 1993, 105, 758; Angew. Chem. Int. Ed. Engl. 1993, 32, 756;
    • (1993) Angew. Chem. Int. Ed. Engl. , vol.32 , pp. 756
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    • note
    • +]; correct C,H elemental analyses for 6, 8, 9.
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    • note
    • -3.
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    • 5] reacts with αC-H acidic ketones at 120°C, forming comparable insertion products. The authors discuss a [2 + 1] cycloaddition of the C-C double bond of the enol to the phosphanediyl complex, followed by a ring-opening rearrangement: Y. Inubushi, N. H. Tran Huy, F. Mathey, Chem. Commun. 1996, 1903.
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    • note
    • 31P = -15.4) could not be completely separated from compound 12 by chromatography or by crystallization. However, since this had no influence on the elemental analysis of 12, the by-product could be a stereoisomer of 12.
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    • 85033140764 scopus 로고    scopus 로고
    • note
    • +]; correct C, H elemental analysis; see comment in ref. [21].
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    • note
    • -3. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-179-141. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: Int. code +(1223) 336-033; e-mail: deposit@chemcrys. cam.ac.uk).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.