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13
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0000718889
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For the first synthesis of an oxaphosphirane tungsten complex by epoxidation of a methylenephosphane tungsten complex, see S. Bauer, A. Marinetti, L. Ricard, F. Mathey, Angew. Chem. 1990, 102, 1188; Angew. Chem. Int. Ed. Engl. 1990, 29, 1166.
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14
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33748241703
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For the first synthesis of an oxaphosphirane tungsten complex by epoxidation of a methylenephosphane tungsten complex, see S. Bauer, A. Marinetti, L. Ricard, F. Mathey, Angew. Chem. 1990, 102, 1188; Angew. Chem. Int. Ed. Engl. 1990, 29, 1166.
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15
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33748216793
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33748216793
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Nucleophilic, terminal phosphanediyl-metal complexes react with aldehydes to form methylenephosphanes: see a) C. C. Cummins, R. R. Schrock, W. M. Davis, Angew. Chem. 1993, 105, 758; Angew. Chem. Int. Ed. Engl. 1993, 32, 756;
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0000924289
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5] has appeared: J. M. Alcaraz, J. Svara, F. Mathey, Nouv. J. Chim. 1986, 10, 321.
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21
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85033142566
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-1
-
-1.
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22
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85033143437
-
-
note
-
+]; correct C,H elemental analyses for 6, 8, 9.
-
-
-
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24
-
-
85033134250
-
-
note
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-3.
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25
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26344450460
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a) R. H. Fogh, S. Larsen, O. Dahl, Acta Crystallogr. Sect. C 1986, 42, 1635;
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Fogh, R.H.1
Larsen, S.2
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26
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0001207046
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b) P. W. N. M. van Leeuwen, C. F. Roobeek, A. G. Orpen, Organometallics, 1990, 9, 2179;
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Van Leeuwen, P.W.N.M.1
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27
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0008736197
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c) T. Kawashima, K. Kato, R. Okazaki, Angew. Chem. 1993, 105, 941; Angew. Chem. Int. Ed. Engl. 1993, 32, 869.
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28
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33748216592
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c) T. Kawashima, K. Kato, R. Okazaki, Angew. Chem. 1993, 105, 941; Angew. Chem. Int. Ed. Engl. 1993, 32, 869.
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30
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0003085106
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-
5] reacts with αC-H acidic ketones at 120°C, forming comparable insertion products. The authors discuss a [2 + 1] cycloaddition of the C-C double bond of the enol to the phosphanediyl complex, followed by a ring-opening rearrangement: Y. Inubushi, N. H. Tran Huy, F. Mathey, Chem. Commun. 1996, 1903.
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Inubushi, Y.1
Tran Huy, N.H.2
Mathey, F.3
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31
-
-
85033139988
-
-
note
-
31P = -15.4) could not be completely separated from compound 12 by chromatography or by crystallization. However, since this had no influence on the elemental analysis of 12, the by-product could be a stereoisomer of 12.
-
-
-
-
32
-
-
85033140764
-
-
note
-
+]; correct C, H elemental analysis; see comment in ref. [21].
-
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33
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0001754788
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E. Niecke, A. Seyer, D.-A. Wildbredt, Angew. Chem. 1981, 93, 687; Angew. Chem. Int. Ed. Engl. 1981, 20, 675.
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36
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37
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-
85033140351
-
-
note
-
-3. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-179-141. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: Int. code +(1223) 336-033; e-mail: deposit@chemcrys. cam.ac.uk).
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