5-exo versus 6-endo intramolecular carbolithiation of N-allyl-N-(2-lithioallyl)amines

Tetrahedron Letters

Volumn 38, Issue 15, 1997, Pages 2763-2766

  Barluenga, José ^a   Sanz, Roberto ^a   Fañanás, Francisco J ^a  

^a UNIVERSITY OF OVIEDO   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

PYRROLIDINE DERIVATIVE;

ARTICLE; CYCLIZATION; DRUG SYNTHESIS; IN VITRO STUDY; METHODOLOGY; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0030953523     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(97)00465-6     Document Type: Article

References (29)

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25. Alternatively, the 5-exo product could rearrange to the 6-endo via a cyclopropyl derivative. See ref. 5.
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29. 13C NMR data.