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To our knowledge, this paper provides the first example of Pd-catalyzed direct carbonylation of arylmethanols promoted by HI, whereas Rh-catalyzed carbonylation of unsubstituted methanol to acetic acid is well-known, see: Forster, D. Adv. Organomet. Chem. 1979, 17, 255.
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0343140804
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note
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1H NMR.
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22
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0343140803
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note
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31P NMR.
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23
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0342271334
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note
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31P NMR and elemental analysis.
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