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Volumn 36, Issue 4, 1997, Pages 374-376

Unusually Stable Organomercury Hydrides and Radicals

Author keywords

Density functional calculations; Hydrides; Mercury; Radicals

Indexed keywords


EID: 0030953007     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199703741     Document Type: Article
Times cited : (13)

References (32)
  • 9
    • 0001145891 scopus 로고
    • a) B. Giese, Angew. Chem. 1985, 97,555; Angew. Chem. Int. Ed. Engl. 1985, 24, 553;
    • (1985) Angew. Chem. , vol.97 , pp. 555
    • Giese, B.1
  • 10
    • 0022101758 scopus 로고
    • a) B. Giese, Angew. Chem. 1985, 97,555; Angew. Chem. Int. Ed. Engl. 1985, 24, 553;
    • (1985) Angew. Chem. Int. Ed. Engl. , vol.24 , pp. 553
  • 18
    • 0642291296 scopus 로고    scopus 로고
    • note
    • 3OH) afforded 2ay and 2az.
  • 19
    • 0642291295 scopus 로고    scopus 로고
    • note
    • 3COOH at 50°C to quantitatively afford the protonolysis product 11 in 20 min). Thus, the rate measurements are always slightly dependent on reaction conditions. This is probably the reason why analytically pure samples have not yet been made.
  • 24
    • 0001510524 scopus 로고
    • The basis set used for Hg is 6-31G(d,p)-SK BJ RECP. ECP: a) W. J. Stevens, M. Krauss, H. Basch, P. G. Jasien, Can. J. Chem. 1992, 70, 612. The 6-31G(d, p) basis set was used for the remaining atoms: b) W. J. Hehre, L. Radom, P. von R. Schleyer, J. A. Pople, Ab Initio Molecular Orbital Theory; Wiley, Chichester, 1986.
    • (1992) Can. J. Chem. , vol.70 , pp. 612
    • Stevens, W.J.1    Krauss, M.2    Basch, H.3    Jasien, P.G.4
  • 25
    • 84873055189 scopus 로고
    • Wiley, Chichester
    • The basis set used for Hg is 6-31G(d,p)-SK BJ RECP. ECP: a) W. J. Stevens, M. Krauss, H. Basch, P. G. Jasien, Can. J. Chem. 1992, 70, 612. The 6-31G(d, p) basis set was used for the remaining atoms: b) W. J. Hehre, L. Radom, P. von R. Schleyer, J. A. Pople, Ab Initio Molecular Orbital Theory; Wiley, Chichester, 1986.
    • (1986) Ab Initio Molecular Orbital Theory
    • Hehre, W.J.1    Radom, L.2    Von Schleyer, P.R.3    Pople, J.A.4
  • 29
    • 0642321714 scopus 로고    scopus 로고
    • note
    • -1.
  • 30
    • 0642352568 scopus 로고    scopus 로고
    • note
    • 3HgH decomposition is related to but not the same as the BDE, which is a measure of the stability of a single isolated molecule.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.