The absolute configuration of (+)-sporochnol A, the fish deterrent from the Caribbean marine alga Sporochnus bolleanus

Tetrahedron Asymmetry

Volumn 8, Issue 8, 1997, Pages 1235-1242

  Takahashi, Michiyasu ^a   Shioura, Yoko ^a   Murakami, Taku ^a   Ogasawara, Kunio ^a  

^a TOHOKU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

TOXIN;

ALGA; ARTICLE; CHIRALITY; DRUG IDENTIFICATION; DRUG ISOLATION; DRUG STRUCTURE; DRUG SYNTHESIS; DRUG TOXICITY; ENANTIOMER; FISH; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; IN VITRO STUDY; PRIORITY JOURNAL;

EID: 0030950489     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0957-4166(97)00119-5     Document Type: Article

References (15)

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2. Optically pure epichlorohydrin is commercially available in both enantiomeric forms from DAISO Corporation, Osaka, Japan. We thank DAISO for the donation of optically pure epichlorohydrin (>98% ee).
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5. Pertinent reviews utilizing optically active O-benzylglycidol in chiral syntheses, see: Takano, S.; Ogasawara, K. J. Syn. Org. Chem. Jpn. 1989, 47, 813-830: Hanson, R. M. Chem. Rev. 1991, 437-475.
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14. Recently, we have completed an alternative asymmetric synthesis of (+)-sporochnol A by employing the fundamentally different procedure which also supported the present conclusion, see: Kamikubo, T.; Shimizu, M.; Ogasawara, K. Enantiomer, in press.
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