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2s on a 12L: 12D cycle.
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84920294477
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note
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- Δ +5.5 mmu ].
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17
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84920294476
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note
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14,15 The derivatives were analyzed by reversed-phase ODS-HPLC: column Cosmosil MS (4.6 × 250 mm) as described above. Retention times of the standards (min); N-Me L-Trp-L-FDAA (47.2), N-Me L-Trp-D-FDAA (48.4). Retention time of N-Me Trp-L-FDAA in the acid hydrolyzate of micropeptin 103 (min): 47.2.
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18
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0342505359
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19
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84920294475
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note
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2O (1:1), and then I,I-bis(trifluoroacetoxy) iodobenzene was added to the solution with stirring at room temparature for 6 h.
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0030590973
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84920294474
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note
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16 Retention time of Glu-L-FDAA (min): 38.2.
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