Chemoselective reduction of vicinal-dihalides with Mg-MeOH via SET

Synthetic Communications

Volumn 27, Issue 10, 1997, Pages 1801-1809

  Khurana, Jitender M ^a,b   Gogia, Amita ^a   Bankhwal, Ramesh K ^a  

^a UNIVERSITY OF DELHI   (India)

^b SRI INTERNATIONAL   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE;

ARTICLE; CHIRALITY; DRUG SYNTHESIS; IN VITRO STUDY; REACTION ANALYSIS;

EID: 0030925804     PISSN: 00397911     EISSN: None     Source Type: Journal    
DOI: 10.1080/00397919708004093     Document Type: Article

References (16)

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13. A reaction of Z-stilbene with Mg-MeOH using 1:20 molar ratio of Z-stilbene to Mg at ambient temperature was monitored and showed the presence of bibenzyl only and no E-stilbene was detected at any stage.
14. The anti-alignment in meso-and d1-III, though favored by orbital symmetry rules, is opposed in the latter case conformationally by a energy difference of 4.4Kcal/mol ; G. Fischer, K. A. Muszkat and E. Fisher, J. Chem. Soc., B, 1156 (1968).
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16. Cyclohexene (96 %) was recovered unchanged after 24 hr from its reaction with Mg-MeOH using 1: 10 molar ratio of cyclohexene : Mg.