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note
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Capacity factor (k′) is used as a retention parameter; k′ = [V(t) -V(o)}/V(o)], where V(t) is the retention volume and V(o) is the dead volum or the retention volume of a nonbinding substrate. This parameter is superic to retention time because it is independent of column size or amount o stationary phase in the column.
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38
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note
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a's obtained from this treatment follow a mono-site Langmuir adsorption model. However, there are clear strong and weak (nonspecific) binding domains present, suggesting that there is not a continuum of binding sites. Mathematical evaluation of the distribution of binding sites in imprinted polymers will be treated elsewhere.
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