Microbial reduction of 2-(6-m-methoxyphenyl-3-oxohexyl)-2,4,4- trimethylcyclopenta-1,3-dione with Schizosaccharomyces pombe (NRRL Y-164)

Tetrahedron Asymmetry

Volumn 8, Issue 18, 1997, Pages 3051-3058

  Lee, Shoei Sheng ^a   Yan, Jiann Long ^a   Wang, K C ^a  

^a NATIONAL TAIWAN UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOPENTANONE DERIVATIVE;

ARTICLE; CHIRALITY; IN VITRO STUDY; INFRARED SPECTROPHOTOMETRY; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PRIORITY JOURNAL; REACTION ANALYSIS; REDUCTION; SCHIZOSACCHAROMYCES POMBE;

EID: 0030921690     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0957-4166(97)00372-8     Document Type: Article

References (7)

1. Lee, Shoei-Sheng; Lin, Gwo-Sen; Wang, K.C. Tetrahedron: Asymmetry, 1996, 7, 1563.
2. Wang, K.C.; Liang, Chang-Hsing; Kan, Wai-Ming; Lee, Shoei-Sheng Bioorg. Med. Chem. 1994, 2, 27.
3. Oppenauer, R.V. Org. Synth., Collective Volume 1955, 3, 207.
4. Bowden, K.; Heilbron, I.M.; Jones, E.R.H.; Weedon, B.C.L. J. Chem. Soc. 1946, 39.
5. Crystal data of (+)-6: orthorhombic p212121; a=6.755(3), b=8.846(7) Å, Z=4. Intensity data were collected on a CAD-4 diffractometer with θ/2θ scan mode, using monochromated MoKα radiation. Data were measured up to 2θ of 140.0°. A total of 2095 reflections were collected. Among them, 1787 were considered to be observed (>2.05 δ (I)). Final agreement indices are R(F)=0.049, RW=0.047, GoF=2.35, based on anisotropic refinement of all non-hydrogen atoms.
6. Crystal data of (+)-8: monoclinic p21; a=5.6743 (II), b=14.254 (6), c=13.857 (6) Å, Z=2. Intensity data were collected on a CAD-4 diffractometer with θ/2θ scan mode, using monochromated MoKα radiation. Data were measured with 2θ range of 30-44°. A total of 2534 reflections were collected. Among them, 1489 were considered to be observed (>2.05 δ (I)). Final agreement indices are RF=0.059, RW=0.062, GoF=1.23, based on anisotropic refinement of all non-hydrogen atoms.
7. Garden, J.B.; Anderson, A.B.; Oliveto, E.P. J. Org. Chem. 1969, 34, 107.