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33646960841
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An OPO laser (MOPO-730 Spectra Physics) pumped by a Nd:YAG laser (GCR 170 Spectra Physics) was employed to excite the porphyrins to the Si states. Temperature was controlled with a Nj gas-flow system (ESDVT3 JEOL).
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10
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33646955839
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note
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1 porphyrin at t = 0. A is a proportionality factor.
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20
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22
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33646964141
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note
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0 ∥ z, respectively.
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23
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0000058338
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26
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33646964836
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19 of the anion radicals of ZnTPP and MgTPP.
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19 of the anion radicals of ZnTPP and MgTPP.
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28
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33646957218
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note
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R = 80 ps with the molecular radius of 5 Å.
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29
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33646956891
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note
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2 in contrast to the cases of MgTPP and ZnTPP. Therefore, the results of E= 0 GHz observed for MgTPP and ZnTPP are not considered to be due to molecular rotations around the z axis.
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