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85081225068
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For an overview of industrial application of Pd, see: Tsuji, J. Synthesis 1990, 739.
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Tsuji, J.1
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0026782148
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0343900922
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note
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8,10
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26
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0001424286
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0342595224
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in press
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Abbott, A. P.; Malkov, A. V.; Zimmermann, N.; Raynor, J. B.; Kočovský, P. Organometallics, in press.
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Enolates of β-dicarbonyls are known to form relatively stable chelate complexes with Mo(II): Brower, D. C.; Winston, P. B.; Tonker, T. L.; Templeton, J. L. Inorg. Chem. 1986, 25, 2883.
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33
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0343029338
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note
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2 at it with 2-5 mol% of the catalyst and a slight excess (1.1 equiv) of the nucleophile. All yields refer to "isolated" yields rather than "GC yields". All new compounds gave satisfactory spectral and analytical data.
-
-
-
-
34
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-
0041147514
-
-
Attempts at developing the Pd(0)-catalyzed reaction of allylic esters with silyl enol ethers derived from simple ketones, as an extension of the established reactions with stabilized C-nucleophiles, have only met with modest success. In the examples reported to date, the more reactive carbonates (rather than acetates) have been employed and some of these reactions seem to work efficiently only as intramolecular processes: (a) Tsuji, J.; Minami, I.; Shimizu, I. Chemistry Lett. 1983, 1325.
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(b) Tsuji, J.; Minami, I.; Shimizu, I. Tetrahedron Lett. 1983, 24, 1793.
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0013553595
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(c) Shimizu, I.; Minami, I.; Tsuji, J. Tetrahedron Lett. 1983, 24, 1797.
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Shimizu, I.1
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0343029337
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note
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+, 242.1670. Found: 242.1670.
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39
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0030602224
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+ reagents: (a) Grieco, P. A.; DuBay, W. J.; Todd, L. J. Tetrahedron Lett. 1996, 37, 8707.
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Todd, L.J.3
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