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Volumn 38, Issue 27, 1997, Pages 4895-4898

Molybdenum(II)-catalyzed allylic substitution

Author keywords

[No Author keywords available]

Indexed keywords

ETHER DERIVATIVE; KETONE; MOLYBDENUM COMPLEX; PALLADIUM COMPLEX;

EID: 0030919825     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(97)01052-6     Document Type: Article
Times cited : (15)

References (40)
  • 4
    • 0000636402 scopus 로고
    • For reviews, see: (a) Trost, B. M. Tetrahedron 1977, 33, 371.
    • (1977) Tetrahedron , vol.33 , pp. 371
    • Trost, B.M.1
  • 10
    • 84855623982 scopus 로고
    • (f) Bäckvall, J.-E. Pure Appl. Chem. 1992, 64, 429; ibid 1992, 64, 429; ibid 1996, 68, 535.
    • (1992) Pure Appl. Chem. , vol.64 , pp. 429
  • 11
    • 84920316284 scopus 로고    scopus 로고
    • (f) Bäckvall, J.-E. Pure Appl. Chem. 1992, 64, 429; ibid 1992, 64, 429; ibid 1996, 68, 535.
    • (1996) Pure Appl. Chem. , vol.68 , pp. 535
  • 13
    • 85081225068 scopus 로고
    • For an overview of industrial application of Pd, see: Tsuji, J. Synthesis 1990, 739.
    • (1990) Synthesis , pp. 739
    • Tsuji, J.1
  • 24
    • 0343900922 scopus 로고    scopus 로고
    • note
    • 8,10
  • 33
    • 0343029338 scopus 로고    scopus 로고
    • note
    • 2 at it with 2-5 mol% of the catalyst and a slight excess (1.1 equiv) of the nucleophile. All yields refer to "isolated" yields rather than "GC yields". All new compounds gave satisfactory spectral and analytical data.
  • 34
    • 0041147514 scopus 로고
    • Attempts at developing the Pd(0)-catalyzed reaction of allylic esters with silyl enol ethers derived from simple ketones, as an extension of the established reactions with stabilized C-nucleophiles, have only met with modest success. In the examples reported to date, the more reactive carbonates (rather than acetates) have been employed and some of these reactions seem to work efficiently only as intramolecular processes: (a) Tsuji, J.; Minami, I.; Shimizu, I. Chemistry Lett. 1983, 1325.
    • (1983) Chemistry Lett. , pp. 1325
    • Tsuji, J.1    Minami, I.2    Shimizu, I.3
  • 38
    • 0343029337 scopus 로고    scopus 로고
    • note
    • +, 242.1670. Found: 242.1670.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.