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0342431441
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note
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Purchased from Aldrich (98% e.e.); the %d.e. of all derived compounds was checked by anal. HPLC.
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13
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0022442161
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16
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0343301046
-
-
note
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3 or otherwise stated for: 4; +24.8 (c=1.2), 6; +71.7 (c=1.0), 8; +1.7 (c=2.0), 9; -18.6 (c=1.7), 10; -27.7 (c=2.0), 12; -14.3 (c=1.7), 14; +6.0 (c=1.0), 15; +14.5 (c=1.0), 16; +29.7 (c=1.0), 18; +27.6 (c=2.9, MeOH), 19; +16.9 (c=1.1), 20; +17.3 (c=1.1), 21; +25.5 (c=0.8), 22; +27.6 (c=1.4), 23; -25.7 (c=1.6), 24; -15.6(c=1.8).
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18
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0024455377
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19
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0342865980
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note
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(b) We thank Professor Okamura for sending us details on the experimental conditions.
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20
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85008556195
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Also oxidation of 3-acetylbicyclo[1.2.3]octane with MCPBA took 8 d
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