Hydrogenation of Ru(1,5-cyclooctadiene)(η3-C3H5)2 over black platinum. A low-temperature reactive deposition of submonolayer quantities of ruthenium atoms on platinum with real time control over surface stoichiometry

Journal of the American Chemical Society

Volumn 119, Issue 15, 1997, Pages 3543-3549

  Lee, Christopher E ^a   Tiege, Paul B ^a   Xing, Yue ^a   Nagendran, Jayan ^a   Bergens, Steven H ^a  

^a UNIVERSITY OF ALBERTA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

PLATINUM; RUTHENIUM COMPLEX;

ADSORPTION; ARTICLE; COMPLEX FORMATION; ELECTRODE; SURFACE PROPERTY;

EID: 0030912652     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja963163p     Document Type: Article

References (82)

1. Miura, H.; Taguchi, H.; Sugiyama, K.; Matsuda, T.; Gonzalez, R. D. J. Catal. 1990, 124, 194.
2. Miura, H.; Gonzalez, R. D. J. Catal. 1982, 74, 216.
3. (a) Radmilovic, V.; Gasteiger, H. A.; Ross, P. N., Jr. J. Catal. 1995, 154, 98.
4. (b) Frelink, T.; Visscher, W.; van Veen, J. A. R. Surf. Sci. 1995, 335, 353.
5. (c) Frelink, T.; Visscher, W.; Cox, A. P.; van Veen, J. A. R. Electrochim. Acta 1995, 40, 1537.
6. (d) Rauhe, B. R., Jr.; McLarnon, F. R.; Cairns, E. J. J. Electrochem. Soc. 1995, 142, 1073.
7. (e) Laborde, H.; Leger, J-M.; Lamy, C. J. Appl. Electrochem. 1994, 24, 1019.
8. (f) Gasteiger, H. A.; Markovic, N.; Ross, P. N., Jr.; Cairns, E. J. J. Electrochem. Soc. 1994, 141, 1795.
9. (g) Gasteiger, H. A.; Markovic, N.; Ross, P. N., Jr.; Cairns, E. J. J. Phys. Chem. 1993, 97, 12020.
10. (h) Herrero, E.; Franaszczuk, K.; Wiecskowski, A. J. Electroanal. Chem. 1993, 361, 269.
11. (i) Hable, C. T.; Wrighton, M. S. Langmuir 1993, 9, 3284.
12. (j) Meli, G.; Leger, J-M.; Lamy, C. J. Appl. Electrochem. 1993, 23, 197.
13. (k) Franaszczuk, K.; Sobkowski, J. J. Electroanal. Chem. 1992, 327, 235.
14. (I) Kennedy, B. J.; Hamnett, A. J. Electroanal. Chem. 1990, 283, 271.
15. (m) Goodenough, J. B.; Hamnett, A., Kennedy, B. J.; Manoharan, R.; Weeks, S. A. J. Electroanal. Chem. 1988, 240, 133.
16. (n) Hughes, V. B.; Miles, R. J. Electroanal. Chem. 1983, 145, 87.
17. (o) Beden, B.; Kadirigan, F; Lamy, C.; Leger, J. M. J. Electroanal. Chem. 1981, 127, 75.
18. (p) Janssen, M. M. P.; Moolhuysen, J. Electrochim. Acta 1976, 21, 869.
19. (q) Surampudi, S.; Narayanan, S. R.; Vamos, E.; Frank, H.; Halpert, G.; LaConti, A.; Kosek, J.; Surya Prakash, G. K.; Olah, G. A. J. Power Sources 1994, 47, 377.
20. (r) Hogarth, M. P.; Munk, J.; Shukula, A. K.; Hamnett, A. J. Appl. Electrochem. 1994, 24, 85.
21. (s) Wasmus, S.; Vielstich, W. J. Appl. Electrochem. 1993, 23, 120.
22. (t) Swathirajan, S.; Mikhail, Y. M. J. Electrochem. Soc. 1991, 138, 1321.
23. (u) Aramata, A.; Masuda, M. J. Electrochem. Soc. 1991, 138, 1949.
24. (v) Iwasita, T.; Nart, F. C.; Vielstich, W. Ber. Bunsen-Ges. Phys. Chem. 1990, 94, 1030.
25. (w) McNicol, B. D.; Short, R. T. J. Electroanal. Chem. 1977, 81, 249.
26. (x) Watanabe, M.; Motoo, S. Electroanal. Interfacial Electrochem. 1975, 60, 267.
27. (a) Shibli, S. M. A.; Noel, M. J. Power Sources 1993, 45, 139.
28. (b) Zou, W.; Gonzalez, R. D. J. Catal. 1992, 133, 202.
29. (c) Wang, S.; Fedkiw, P. S. J. Electrochem. Soc. 1992, 139, 2519.
30. (d) Machida, K.; Fukuoka, A.; Ichikawa, M.; Enyo, M. J. Electrochem. Soc. 1991, 138, 1958.
31. (e) Hamnett, A.; Weeks, A. A.; Kennedy, B. J.; Troughton, G.; Christensen, P. A. Ber. Bunsen-Ges. Phys. Chem. 1990, 94, 1014.
32. (f) Alerasool, S.; Gonzalez, R. D. J. Catal. 1990, 124, 204.
33. (g) Kunimatsu, K. Ber. Bunsen-Ges. Phys. Chem. 1990, 94, 1025.
34. (h) Alerasool, S.; Boecker, D.; Rejai, B.; Gonzalez, R. D.; Del Angel, G.; Azomosa, M.; Gomez, R. Langmuir 1988, 4, 1083.
35. (i) Watanabe, M.; Uchida, M.; Motoo, S. J. Electroanal. Chem. 1987, 229, 395.
36. (j) Furuya, N.; Motoo, S. J. Electroanal. Chem. 1984, 179, 303.
37. (k) Miura, H.; Gonzalez, R. D. J. Catal. 1982, 74, 216.
38. McNicol B. D. J. Electroanal. Chem. 1981, 118, 71.
39. (m) Ross, P. N.; Kinoshita, K.; Scarpellino, A. J.; Stonehart, P. J. Electroanal. Chem. 1975, 63, 97.
40. (n) Harubumi, E. Jpn. Kokai Tokkyo Koho JP 04,118,860 [92,118,860]; Chem. Abstr. 117:115219.
41. (o) Del Angel, G.; Alerasool, S.; Dominguez, J. M.; Gonzalez, R. D.; Gomez, R. Surf. Sci. 1989, 224, 407.
42. (p) Miura, H.; Suzuki, T.; Ushikubo, Y; Sugiyama, K.; Matsuda, T.; Gonzalez, R. D. J. Catal. 1984, 55, 331.
43. (a) Hadzi-Jordanov, S.; Angerstein-Kozlowska, H.; Vukovic, M.; Conway, J. J. Electrochem. Soc. 1978, 125, 1471.
44. (b) Kotz, R.; Stucki, S. J. Electrochem. Soc. 1984, 172, 211.
45. (c) Vukovic, M. J. Chem. Soc., Faraday Trans. 1990, 86, 3743.
46. (d) Entine, V. S.; Petrii, O. A. Elektrokhimiya 1968, 4, 678.
47. (e) Beden, B.; Kadirgan, F.; Lamy, C.; Leger, J. M. J. Electroanal. Chem. 1981, 127, 75.
48. 7
49. (a) Lesage, P.; Clause, O.; Moral, P.; Didillon, B.; Candy, J. P.; Basset, J.M. J. Catal. 1995, 155, 238.
50. (b) Candy, J. P.; Didillon, B.; Smith, E. L.; Shay, T. B.; Basset, J. M. J. Mol. Catal. 1994, 86, 179.
51. (c) Didillon, B.; Houtman, C.; Shay, T.; Candy, J. P.; Basset, J. M. J. Am. Chem. Soc. 1993, 115, 9381.
52. (d) Basset, J. M.; Candy, J. P.; Choplin, A.; Santini, C.; Theolier, A. Catal. Today 1989, 6, 1.
53. (e) Agnelli, M.; Louessard, P.; El Mansour, A.; Candy, J. P.; Bournonville, J. P.; Basset, J. M. Catal. Today 1989, 6, 63.
54. Miller, T. M.; Izumi, A. N.; Shih, Y. S.; Whitesides, G. M. J. Am. Chem. Soc. 1988, 110, 3146. Miller, T. M.; McCarthy, T. J. Whitesides, G. M. J. Am. Chem. Soc. 1988, 110, 3156. Miller, T. M.; Whitesides, G. M. J. Am. Chem. Soc. 1988, 110, 3164.
55. Miller, T. M.; Izumi, A. N.; Shih, Y. S.; Whitesides, G. M. J. Am. Chem. Soc. 1988, 110, 3146. Miller, T. M.; McCarthy, T. J. Whitesides, G. M. J. Am. Chem. Soc. 1988, 110, 3156. Miller, T. M.; Whitesides, G. M. J. Am. Chem. Soc. 1988, 110, 3164.
56. Miller, T. M.; Izumi, A. N.; Shih, Y. S.; Whitesides, G. M. J. Am. Chem. Soc. 1988, 110, 3146. Miller, T. M.; McCarthy, T. J. Whitesides, G. M. J. Am. Chem. Soc. 1988, 110, 3156. Miller, T. M.; Whitesides, G. M. J. Am. Chem. Soc. 1988, 110, 3164.
57. Albert, M. O.; Singleton, E.; Yates, J. E. Inorg. Synth. 1989, 26, 249.
58. A shiny 52 mesh platinum gauze was connected to a platinum wire that was sealed to a uranium glass tube. The gauze was blacked as described in DiCosimo, R.; Whitesides, G. M. J. Phys. Chem. 1989, 93, 768.
59. Woods, R. Electroanal. Chem. Interfacial. Electrochem. 1974, 49, 217.
60. Use of prepurified water to protect platinum surfaces during transfer in air is an established technique often used in electrochemistry with platinum electrodes. See: Clavilier, J.; Faure, R.; Guinet, G. Durand, R. J. Electroanal. Chem. 1980, 107, 205.
61. 1H NMR spectroscopy.
62. Identified using GC but not quantified.
63. (a) Gasteiger, H. A.; Markovic, N.; Ross, P. N., Jr.; Cairns, E. J. J. Phys. Chem. 1994, 98, 617.
64. (b) Richarz, F.; Wohlmann, B.; Vogel, U.; Hoffschulz, Wandelt, K. Surf. Sci. 1995, 335, 361.
65. The metallic radii of platium and ruthenium are 139 and 134 pm, respectively. See: Tables of Physical and Chemical Constants, 15th ed.; Kaye, G. W. C., Laby, T. H., Eds.; Longman Inc: New York, 1986.
66. (a) Kinoshita, K.; Ross, P. N. J. Electroanal. Chem. 1977, 78, 313.
67. (b) Bett, J.; Kinoshita, K.; Routis, K.; Stonehart, P. J. Catal. 1973, 29, 160.
68. For a related procedure see: Connick, R. E.; Hurley, R. J. Am. Chem. Soc. 1952, 74, 5012.
69. 2/g.
70. Watanabe, M.; Motoo, S. Electroanal. Chem. Interfacial Electrochem. 1975, 60, 267.
71. Franaszczuk, K.; Sobkowski, J. J. Electroanal. Chem. 1992, 327, 235. Wang, S.; Fedkiw, P. S. J. Electrochem. Soc. 1992, 139, 2519.
72. Franaszczuk, K.; Sobkowski, J. J. Electroanal. Chem. 1992, 327, 235. Wang, S.; Fedkiw, P. S. J. Electrochem. Soc. 1992, 139, 2519.
73. Iwasita, T.; Nart, F. C.; Vielstich Ber. Bunsen-Ges. Phys. Chem. 1990, 94, 1030. Kunimatsu, K. Ber. Bunsen-Ges. Phys. Chem. 1990, 94, 1025. Wasmus, S.; Vielstich, W. J. Appl. Electrochem. 1993, 23, 120.
74. Iwasita, T.; Nart, F. C.; Vielstich Ber. Bunsen-Ges. Phys. Chem. 1990, 94, 1030. Kunimatsu, K. Ber. Bunsen-Ges. Phys. Chem. 1990, 94, 1025. Wasmus, S.; Vielstich, W. J. Appl. Electrochem. 1993, 23, 120.
75. Iwasita, T.; Nart, F. C.; Vielstich Ber. Bunsen-Ges. Phys. Chem. 1990, 94, 1030. Kunimatsu, K. Ber. Bunsen-Ges. Phys. Chem. 1990, 94, 1025. Wasmus, S.; Vielstich, W. J. Appl. Electrochem. 1993, 23, 120.
76. A low-energy deposition related to hydrogenation of 1 is electroless deposition. For examples, see: Lamouche, D.; Clechet, P.; Martin, J. R.; Haroutiounian, E.; Sandino, J. P. I. J. Electrochem. Soc.: Solid-State Sci. Technol. 1987, 134, 692. Baum, T. H. J. Electrochem. Soc. 1990, 137, 252. Stremsdoerfer, G.; Martin, J. R.; Clechet, P.; Nguyen-Du. J. Electrochem. Soc. 1990, 137, 256. Murphy, M. M.; Van herle, J.; McEvoy, A. J.; Thampi, K. R. J. Electrochem. Soc. 1994, 141, L94. Wang, Y. F.; Pollard, R. J. Electrochem. Soc. 1995, 142, 1712 and references cited therein. As far as we are aware, control over submonolayer quantities of adatoms has not been achieved with electroless deposition.
77. A low-energy deposition related to hydrogenation of 1 is electroless deposition. For examples, see: Lamouche, D.; Clechet, P.; Martin, J. R.; Haroutiounian, E.; Sandino, J. P. I. J. Electrochem. Soc.: Solid-State Sci. Technol. 1987, 134, 692. Baum, T. H. J. Electrochem. Soc. 1990, 137, 252. Stremsdoerfer, G.; Martin, J. R.; Clechet, P.; Nguyen-Du. J. Electrochem. Soc. 1990, 137, 256. Murphy, M. M.; Van herle, J.; McEvoy, A. J.; Thampi, K. R. J. Electrochem. Soc. 1994, 141, L94. Wang, Y. F.; Pollard, R. J. Electrochem. Soc. 1995, 142, 1712 and references cited therein. As far as we are aware, control over submonolayer quantities of adatoms has not been achieved with electroless deposition.
78. A low-energy deposition related to hydrogenation of 1 is electroless deposition. For examples, see: Lamouche, D.; Clechet, P.; Martin, J. R.; Haroutiounian, E.; Sandino, J. P. I. J. Electrochem. Soc.: Solid-State Sci. Technol. 1987, 134, 692. Baum, T. H. J. Electrochem. Soc. 1990, 137, 252. Stremsdoerfer, G.; Martin, J. R.; Clechet, P.; Nguyen-Du. J. Electrochem. Soc. 1990, 137, 256. Murphy, M. M.; Van herle, J.; McEvoy, A. J.; Thampi, K. R. J. Electrochem. Soc. 1994, 141, L94. Wang, Y. F.; Pollard, R. J. Electrochem. Soc. 1995, 142, 1712 and references cited therein. As far as we are aware, control over submonolayer quantities of adatoms has not been achieved with electroless deposition.
79. A low-energy deposition related to hydrogenation of 1 is electroless deposition. For examples, see: Lamouche, D.; Clechet, P.; Martin, J. R.; Haroutiounian, E.; Sandino, J. P. I. J. Electrochem. Soc.: Solid-State Sci. Technol. 1987, 134, 692. Baum, T. H. J. Electrochem. Soc. 1990, 137, 252. Stremsdoerfer, G.; Martin, J. R.; Clechet, P.; Nguyen-Du. J. Electrochem. Soc. 1990, 137, 256. Murphy, M. M.; Van herle, J.; McEvoy, A. J.; Thampi, K. R. J. Electrochem. Soc. 1994, 141, L94. Wang, Y. F.; Pollard, R. J. Electrochem. Soc. 1995, 142, 1712 and references cited therein. As far as we are aware, control over submonolayer quantities of adatoms has not been achieved with electroless deposition.
80. A low-energy deposition related to hydrogenation of 1 is electroless deposition. For examples, see: Lamouche, D.; Clechet, P.; Martin, J. R.; Haroutiounian, E.; Sandino, J. P. I. J. Electrochem. Soc.: Solid-State Sci. Technol. 1987, 134, 692. Baum, T. H. J. Electrochem. Soc. 1990, 137, 252. Stremsdoerfer, G.; Martin, J. R.; Clechet, P.; Nguyen-Du. J. Electrochem. Soc. 1990, 137, 256. Murphy, M. M.; Van herle, J.; McEvoy, A. J.; Thampi, K. R. J. Electrochem. Soc. 1994, 141, L94. Wang, Y. F.; Pollard, R. J. Electrochem. Soc. 1995, 142, 1712 and references cited therein. As far as we are aware, control over submonolayer quantities of adatoms has not been achieved with electroless deposition.
81. With the aid of a calibrated strobe light.
82. Connick, R. E.; Hurley, C. R. J. Am. Chem. Soc. 1952, 74, 5012.