Highly diastereoselective reduction of bicyclic and steroidal conjugated enones with DIBAL in THF-DME

Synthetic Communications

Volumn 27, Issue 11, 1997, Pages 1969-1973

  Saito, Akiko ^a   Tanaka, Akira ^a   Oritani, Takayuki ^a  

^a TOHOKU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYL COMPOUND; STEROID;

ARTICLE; DRUG SYNTHESIS; REDUCTION; STEREOCHEMISTRY;

EID: 0030907056     PISSN: 00397911     EISSN: None     Source Type: Journal    
DOI: 10.1080/00397919708006799     Document Type: Article

References (5)

1. 4 in ether led to an inseparable diastereomeric mixture of allylic alcohol 9 with a ratio of 4:1. Klix, R. C., Bach, R. D., J. Org. Chem., 1989, 52, 580.
2. Saito, A., Tanaka, A., Oritani, T., Tetrahedron:Asymmetry, 1996, 7, 2923.
3. Oritani, T., Yamashita, K., Agric. Biol. Chem., 1980, 44, 2637.
4. Collins, D. J., J. Chem. Soc., 1959, 3919.
5. Sondheimer, F., Klibansky, Y., Tetrahedron, 1959, 5, 15.