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The reaction of 1-phenyl-3-tributylstannylprop-1-ene with 2c(2 equiv) using copper(I) iodide (2 equiv) for 24 h gave the allylated product only in 11 % yield. No allylated product was obtained by the similar reaction of 2-methyl-6-phenyl-4-tributylstannythex-2-ene with 2c.
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Yamamoto et al. reported that the reaction of isopropylthioallylcopper, prepared by the treatment of isopropylthioallyllithium with copper(I) iodide, with allylic bromides regioselectively gave γ-allylated products; Oshima, K.; Yamamoto, H.; Nozaki, H. J. Am. Chem. Soc. 1973, 95, 7926.
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