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Volumn 36, Issue 3, 1997, Pages 265-266

Dihydrogen Formation in a Trihydride Metallocene and Its Elimination, Both Assisted by Lewis Acids: The [Cp2NbH3] + BH3 System

Author keywords

Ab initio calculations; Dihydrogen complexes; Hydrido complexes; Lewis acids; Niobium

Indexed keywords


EID: 0030902126     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199702651     Document Type: Article
Times cited : (19)

References (38)
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  • 3
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    • Recent reviews: a) P. J. Jessop, R. H. Morris, Coord. Chem. Rev. 1992, 121, 155; b) D. M. Heinekey, W. J. Oldham, Jr., Chem. Rev. 1993, 93, 913; c) R. H. Crabtree, Angew. Chem. 1993, 105, 828; Angew. Chem. Int. Ed. Engl. 1993, 32, 789.
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    • Heinekey, D.M.1    Oldham Jr., W.J.2
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    • Recent reviews: a) P. J. Jessop, R. H. Morris, Coord. Chem. Rev. 1992, 121, 155; b) D. M. Heinekey, W. J. Oldham, Jr., Chem. Rev. 1993, 93, 913; c) R. H. Crabtree, Angew. Chem. 1993, 105, 828; Angew. Chem. Int. Ed. Engl. 1993, 32, 789.
    • (1993) Angew. Chem. , vol.105 , pp. 828
    • Crabtree, R.H.1
  • 5
    • 33745385639 scopus 로고
    • Recent reviews: a) P. J. Jessop, R. H. Morris, Coord. Chem. Rev. 1992, 121, 155; b) D. M. Heinekey, W. J. Oldham, Jr., Chem. Rev. 1993, 93, 913; c) R. H. Crabtree, Angew. Chem. 1993, 105, 828; Angew. Chem. Int. Ed. Engl. 1993, 32, 789.
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    • b) H.-H. Limbach, M. Maurer, G. Scherer, B. Chaudret, Angew. Chem. 1992, 1414; Angew. Chem. Int. Ed. Engl. 1992, 31, 1369;
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    • (Eds.: G. Wilkinson, F. G. A. Stone, E. W. Abel), Pergamon Press
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    • Labinger, J.A.1
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    • note
    • 5v symmetry. The stationary points were located with the Schlegel gradient minimization algorithm [15]. If the approximate derivative matrix is forced to contain zero or a single negative eigenvalue, the optimization converges to a minimum or a transition state, respectively.
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    • note
    • 3 group, and for the hydrogen atoms directly attached to the metal [17b,c,d]. The double-ζ 6-31G valence basis set was used for the C and H atoms of the Cp ligands [17e].
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    • A. Haaland, Angew. Chem. 1989, 101, 1017; Angew. Chem., Int. Ed. Engl. 1989, 28, 992.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.