Physical organic chemistry of transition metal carbene complexes. 7. Kinetics of hydrolysis of (CO)5M = C(OR)Ph (M = Cr, W; R = Me, Et) and (CO)5Cr = (OMe)CH = CHPh in aqueous acetonitrile

Journal of the American Chemical Society

Volumn 119, Issue 9, 1997, Pages 2103-2110

  Bernasconi, Claude F ^a   Flores, Francis X ^a   Kittredge, Kevin W ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHROMIUM; METAL COMPLEX; TUNGSTEN;

ARTICLE; COMPLEX FORMATION; HYDROLYSIS; IN VITRO STUDY; PH; REACTION ANALYSIS; SPECTROPHOTOMETRY;

EID: 0030892426     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja963617i     Document Type: Article

References (30)

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4. For recent reviews see: (a) Dötz, K. H.; Fischer, H.; Hofmann, P.; Kreissl, F. R.; Schubert, U.; Weiss, K. Transition Metal Carbene Complexes; Verlag Chemie: Deerfield Beach, FL, 1983. (b) Dötz, K. H. Angew. Chem., Int. Ed. Engl. 1984, 23, 587. (c) Gallop, M. A.; Roper, W. R. Adv. Organomet. Chem. 1986, 25, 121. (d) Wulff, W. D. Adv. Met.-Org. Chem. 1989, 1, 209. (e) Schubert, U., Ed. Advances in Metal Carbene Chemistry; Kluwer: Dordrecht, Holland, 1989. (f) Dötz, K. H. New J. Chem. 1990, 14, 433. (g) Wulff, W. D. In Comprehensive Organic Synthesis; Trost, B. M., Fleming, I., Eds.; Pergamon Press: New York, 1990; Vol. 5. (h) Schmidt, M. A.; Miller, J. R.; Hegedus, L. S. J. Organomet. Chem. 1991, 413, 143. (i) Veillard, A. Chem. Rev. 1991, 91, 743.
5. For recent reviews see: (a) Dötz, K. H.; Fischer, H.; Hofmann, P.; Kreissl, F. R.; Schubert, U.; Weiss, K. Transition Metal Carbene Complexes; Verlag Chemie: Deerfield Beach, FL, 1983. (b) Dötz, K. H. Angew. Chem., Int. Ed. Engl. 1984, 23, 587. (c) Gallop, M. A.; Roper, W. R. Adv. Organomet. Chem. 1986, 25, 121. (d) Wulff, W. D. Adv. Met.-Org. Chem. 1989, 1, 209. (e) Schubert, U., Ed. Advances in Metal Carbene Chemistry; Kluwer: Dordrecht, Holland, 1989. (f) Dötz, K. H. New J. Chem. 1990, 14, 433. (g) Wulff, W. D. In Comprehensive Organic Synthesis; Trost, B. M., Fleming, I., Eds.; Pergamon Press: New York, 1990; Vol. 5. (h) Schmidt, M. A.; Miller, J. R.; Hegedus, L. S. J. Organomet. Chem. 1991, 413, 143. (i) Veillard, A. Chem. Rev. 1991, 91, 743.
6. For recent reviews see: (a) Dötz, K. H.; Fischer, H.; Hofmann, P.; Kreissl, F. R.; Schubert, U.; Weiss, K. Transition Metal Carbene Complexes; Verlag Chemie: Deerfield Beach, FL, 1983. (b) Dötz, K. H. Angew. Chem., Int. Ed. Engl. 1984, 23, 587. (c) Gallop, M. A.; Roper, W. R. Adv. Organomet. Chem. 1986, 25, 121. (d) Wulff, W. D. Adv. Met.-Org. Chem. 1989, 1, 209. (e) Schubert, U., Ed. Advances in Metal Carbene Chemistry; Kluwer: Dordrecht, Holland, 1989. (f) Dötz, K. H. New J. Chem. 1990, 14, 433. (g) Wulff, W. D. In Comprehensive Organic Synthesis; Trost, B. M., Fleming, I., Eds.; Pergamon Press: New York, 1990; Vol. 5. (h) Schmidt, M. A.; Miller, J. R.; Hegedus, L. S. J. Organomet. Chem. 1991, 413, 143. (i) Veillard, A. Chem. Rev. 1991, 91, 743.
7. For recent reviews see: (a) Dötz, K. H.; Fischer, H.; Hofmann, P.; Kreissl, F. R.; Schubert, U.; Weiss, K. Transition Metal Carbene Complexes; Verlag Chemie: Deerfield Beach, FL, 1983. (b) Dötz, K. H. Angew. Chem., Int. Ed. Engl. 1984, 23, 587. (c) Gallop, M. A.; Roper, W. R. Adv. Organomet. Chem. 1986, 25, 121. (d) Wulff, W. D. Adv. Met.-Org. Chem. 1989, 1, 209. (e) Schubert, U., Ed. Advances in Metal Carbene Chemistry; Kluwer: Dordrecht, Holland, 1989. (f) Dötz, K. H. New J. Chem. 1990, 14, 433. (g) Wulff, W. D. In Comprehensive Organic Synthesis; Trost, B. M., Fleming, I., Eds.; Pergamon Press: New York, 1990; Vol. 5. (h) Schmidt, M. A.; Miller, J. R.; Hegedus, L. S. J. Organomet. Chem. 1991, 413, 143. (i) Veillard, A. Chem. Rev. 1991, 91, 743.
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15. 1
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19. See paragraph concerning supporting information at the end of this paper.
20. 5CrX under the same reaction conditions has been published in ref 1.
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24. 15
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28. 19
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30. OH should be less dramatic.