Enantiomeric purity of alkylmethylphenylsulfonium ions with chiral NMR shift reagents: Racemization by pyramidal inversion as observed by 1H NMR spectroscopy

Tetrahedron Asymmetry

Volumn 8, Issue 19, 1997, Pages 3175-3181

  Green, Thomas K ^a   Whetstine, Johnathan R ^a   Son, Ea Ji Ru ^a  

^a WESTERN KENTUCKY UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

SULFONIUM DERIVATIVE;

ARTICLE; DRUG STRUCTURE; ENANTIOMER; IN VITRO STUDY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PRIORITY JOURNAL; RACEMIC MIXTURE;

EID: 0030882112     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0957-4166(97)00383-2     Document Type: Article

References (8)

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4. Andersen, K. K.; Caret, R. L.; Nielsen-Karup, J. Am. Chem. Soc. 1974, 96, 8026.
5. Snipe, A. C. The Chemistry of the Sulphonium Group C. J. M. Stirling and S. Patai, eds, John Wiley, New York, 1981, Chapter 12, pp. 317-318.
6. Darwish, D.; Tourigny, G. J. Am. Chem. Soc. 1966, 88, 4303.
7. Darwish, D.; Hui, S. H.; Tomlinson, R. J. Am. Chem. Soc. 1968, 90, 5631-5632.
8. Scastazzua, R.; Mislow, K.; Tetrahedron Letters 1967, 2719.