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Polished thin sections of 20 μm thickness were used for optical, SEM, and microprobe investigations. Selected regions were then removed and prepared for TEM by ion-bombardment thinning. In order to minimize the damage to unstable compounds that can occur from heating and ion bombardment, the samples were prepared without the use of thermal adhesives, and ion milling was done using a liquid-nitrogen-cooled specimen holder. The low-temperature sample-preparation techniques were applied to samples studied in Bayreuth as well as selected samples studied previously in Münster. TEM was performed using Philips CM20 and CM20-FEG instruments operated at 200 kV, and both instruments were equipped with Noran Voyager analytical systems for energy-dispersive x-ray spectroscopy (EDS).
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We thank two anonymous reviewers for helpful suggestions in the improvement of the manuscript. This work is part of a Ph.D. thesis (C.M.L.) at the Institut für Planetologie, Westfälische Wilhelms-Universität, Münster. It was partially supported by the Deutsche Forschungsgemeinschaft (DFG).
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