Absolute configuration and conformation of 1,1':4',1'-ternaphthalene compounds as determined by X-ray crystallography

Enantiomer

Volumn 2, Issue 2, 1997, Pages 123-126

  Harada, Nobuyuki ^a   Vassilev, Vassil P ^a   Hiyoshi, Norie ^a  

^a TOHOKU UNIVERSITY   (Japan)

Author keywords

1,1':4',1' Ternaphthalene; Absolute configuration; Chiral phthalic acid amide method; Enantioresolution; X ray crystallographic analysis

Indexed keywords

NAPHTHALENE DERIVATIVE;

CHIRALITY; CIRCULAR DICHROISM; DERIVATIZATION; DRUG STRUCTURE; IN VITRO STUDY; PRIORITY JOURNAL; SHORT SURVEY; STEREOCHEMISTRY; X RAY CRYSTALLOGRAPHY;

EID: 0030859280     PISSN: 10242430     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Short Survey

References (10)

1. Harada, N., Nehira, T., Soutome, T., Hiyoshi, N. and Kido, F. (1996). Enantiomer, 1, 35-39.
2. Harada, N., Soutome, T., Nehira, T., Uda, H., Oi, S., Okamura, A. and Miyano, S. (1993). J. Am. Chem. Soc., 115, 7547-7548.
3. Hayashi, T., Hayashizaki, K. and Ito, Y. (1989). Tetrahedron Lett., 30, 215-218.
4. Belohradsky, M., Budesinsky, M., Gunterova, J., Hodacova, J., Holy, P., Zavada, J., Cisarova, I. and Podlaha, J. (1996). J. Org. Chem., 61, 1205-1210.
5. Harada, N., Hiyoshi, N., Vassilev, V. P. and Hayashi, T. (1996). Chirality, in press.
6. Harada, N. and Nakanishi, K. (1983). Circular Dichroic Spectroscopy - Exciton Coupling in Organic Stereochemistry, University Science Books, Mill Valley, California, and Oxford University Press, Oxford.
7. 3) δ 0.87 (6 H, s), 1.05 (6 H, s), 1.1-2.0 (12 H, m), 2.40 (2 H, m), 3.31 (2 H, d, J = 14.3 Hz), 3.33 (2 H, d, J = 14.3 Hz), 3.64 (2 H, m), 5.29 (4 H, s), 7.19-7.35 (10 H, m), 7.40-7.54 (6 H, m), 7.59 (2 H, d, J = 7.8 Hz), 7.60 (2 H, s), 7.78 (2 H, d, J = 8.5 Hz), 7.93 (2 H, d, J = 8.0 Hz), 8.01 (2 H, d, J = 8.5 Hz).
8. 3) δ 0.87 (6 H, s), 1.10 (6 H, s), 1.31 (4 H, m), 1.70 (2 H, m), 1.82 (4 H, m), 1.95 (2 H, m), 2.09 (2 H, m), 2.43 (2 H, m), 3.33 (2 H, d, J = 14.3 Hz), 3.34 (2 H, d, J = 14.3 Hz), 3.88 (2 H, m), 5.26 (4 H, s), 7.21-7.33 (8 H, m), 7.42 (4 H, m), 7.47-7.54 (4 H, m), 7.66 (2 H, s), 7.81 (4 H, d, J = 8.4 Hz), 7.94 (2 H, d, J = 8.1 Hz), 8.01 (2 H, d, J = 8.4 Hz).
9. 2: C, 64.35; H, 4.61; Cl, 11.17; N, 2.21; S, 5.05. Found: C, 64.53; H, 4.79; Cl, 10.90; N, 2.34; S, 5.37.
10. 2: C, 64.35; H, 4.61; Cl, 11.17; N, 2.21; S, 5.05. Found: C, 64.58; H, 4.77; Cl, 10.88; N, 2.34; S, 5.16.