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Volumn 62, Issue 12, 1997, Pages 3984-3988

Enantioselective total synthesis of (+)-eutypoxide B

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOHEXANE DERIVATIVE; EUTYPOXIDE B; MYCOTOXIN; UNCLASSIFIED DRUG;

EID: 0030851937     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo9617326     Document Type: Article
Times cited : (47)

References (36)
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    • note
    • The ease with which this elimination occurs is probably due to the boat conformation of the cyclohexane ring which is imposed by the isopropylidene acetal ring. In unconstrained systems this elimination occurs less readily. See ref 13.
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    • Cerium could also function in a similar way to zinc but without the consequent ring opening
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