Intra-Cavity Inclusion of [CpFeII(arene)]+ Guests by Cyclotriveratrylene

Angewandte Chemie (International Edition in English)

Volumn 36, Issue 16, 1997, Pages 1736-1738

  Holman, K Travis ^a   Steed, Jonathan W ^b   Atwood, Jerry L ^a  

^a UNIVERSITY OF MISSOURI   (United States)

^b KING'S COLLEGE LONDON   (United Kingdom)

Author keywords

Cryptophane; Host guest chemistry; Inclusion compounds; Molecular recognition; Sandwich complexes

Indexed keywords

EID: 0030850530     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199717361     Document Type: Article

References (26)

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2. A. Collet, Tetrahedron 1987, 43, 5725; in Inclusion Compounds, Vol. 2 (Eds.: J. L. Atwood, J. E. D. Davies, D. D. MacNicol), Academic Press, London, 1984, pp. 97-121; A. Collet, J.-P. Dutasta, B. Lozach, J. Canceill, Top. Curr. Chem. 1993, 165, 103.
3. A. Collet, Tetrahedron 1987, 43, 5725; in Inclusion Compounds, Vol. 2 (Eds.: J. L. Atwood, J. E. D. Davies, D. D. MacNicol), Academic Press, London, 1984, pp. 97-121; A. Collet, J.-P. Dutasta, B. Lozach, J. Canceill, Top. Curr. Chem. 1993, 165, 103.
4. Recent reviews on these compounds: A. Collet in Comprehensive Supramolecular Chemistry, Vol. 6 (Eds.: D. D. MacNicol, F. Toda, R. Bishop), Pergamon, Oxford, 1996, pp. 281-303.
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12. K. T. Holman, M. M. Halihan, J. W. Steed, S. S. Jurisson, J. L. Atwood, J. Am. Chem. Soc. 1995, 117, 7848; K. T. Holman, M. M. Halihan, S. S. Jurisson, J. L. Atwood, R. S. Burkhalter, A. R. Mitchell, J. W. Steed, ibid. 1996, 118, 9567; J. L. Atwood, K. T. Holman, J. W. Steed, Chem. Commun. 1996, 1401.
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15. R. J. Blanch, M. Williams, G. D. Fallon, M. G. Gardiner, R. Kaddour, C. L. Raston. Angew. Chem. 1997, 109, 520; Angew. Chem. Int. Ed. Engl. 1997, 36, 504.
16. Of the abundance of literature concerning 18-electron iron-containing sandwich complexes, see, for example: R. E. Lehmann, J. K. Kochi, J. Am. Chem. Soc. 1991, 113, 501.
17. G. R. Desiraju, Angew. Chem. 1995, 107, 2541; Angew. Chem. Int. Ed. Engl. 1995, 34, 2311.
18. G. R. Desiraju, Angew. Chem. 1995, 107, 2541; Angew. Chem. Int. Ed. Engl. 1995, 34, 2311.
19. -1, 3<2θ<46° T=298 K. Final refinement converged with R=0.1009 and wR2=0.2651 for 2196 (I>2σ[I]) of 2884 unique reflections and 438 parameters. Crystallographic data (excluding structure factors) for these structures reported in this paper have been deposited to the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-100191. Copies of the data can be obtained free of charge on application to the Director, CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: int. code+(1223)336-033; e-mail: teched@chemcrys.cam.ac.uk).
20. The deligation reaction mediated by visible light may proceed very efficiently, with high quantum yields, depending on the arene, temperature, solvent, and anion: A. M. McNair, J. L. Schrenk, K. R. Mann. Inorg. Chem. 1984, 23, 2633.
21. D. Y. Curtin, I. C. Paul, Chem. Rev. 1981, 81, 525.
22. 2. The concentration of CTV was held constant at about 0.03 M while varying the concentration of added guest from 0-0.3 M.
23. 0=-1.55 V (potentials vs. the saturated calomel electrode). For reference to this data, and that of similar compounds, see D. Astruc, Electron Transfer and Radical Processes in Transition-Metal Chemistry, VCH, New York, 1995, pp. 148.
24. J. L. Atwood, G. A. Koutsantonis, C. L. Raston, Nature 1994, 368, 229.
25. a) G. M. Sheldrick, Acta Crystallogr. Sect. A 1990, 46, 467;
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