Isomers of the Elemental Composition CN2O

Angewandte Chemie (International Edition in English)

Volumn 36, Issue 16, 1997, Pages 1707-1709

  Maier, Günther ^a   Reisenauer, Hans Peter ^a   Eckwert, Jürgen ^a   Naumann, Matthias ^a   De Marco, Michael ^a  

^a UNIVERSITY HOSPITAL GIESSEN   (Germany)

Author keywords

Ab initio calculations; Isomerizations; Matrix isolation; Photochemistry; Radicals

Indexed keywords

EID: 0030850527     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199717071     Document Type: Article

References (18)

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7. The reaction of F atoms with NO leads to both possible isomers, ONF and the "inorganic" isonitrosyl compound NOF. The latter yields the thermodynamically more stable nitrosyl isomer upon irradiation in a matrix at 8 K: R. R. Smardzewski, W. B. Fox, J. Chem. Soc. Chem. Commun. 1974, 241-242; J. Chem. Phys. 1974, 60, 2104-2110.
8. The reaction of F atoms with NO leads to both possible isomers, ONF and the "inorganic" isonitrosyl compound NOF. The latter yields the thermodynamically more stable nitrosyl isomer upon irradiation in a matrix at 8 K: R. R. Smardzewski, W. B. Fox, J. Chem. Soc. Chem. Commun. 1974, 241-242; J. Chem. Phys. 1974, 60, 2104-2110.
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17. G. Herzberg, Spectra of Diatomic Molecules, Van Nostrand, Princeton, 1950.
18. -1) upon irradiation at λ = 193 nm. The reverse reaction is initiated with light of wavelength λ > 310 nm: M. De Marco, Diplomarbeit, Universität Giessen, Germany, 1996.