A novel efficient synthesis of dihydroxyacetone phosphate and bromoacetol phosphate for use in enzymatic aldol syntheses

Journal of Organic Chemistry

Volumn 62, Issue 17, 1997, Pages 5920-5922

  Gefflaut, Thierry ^a   Lemaire, Marielle ^a   Valentin, Marie Lise ^a   Bolte, Jean ^a  

^a UNIVERSITÉ CLERMONT AUVERGNE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

3 BROMOACETOL PHOSPHATE; DIHYDROXYACETONE PHOSPHATE; FRUCTOSE BISPHOSPHATE ALDOLASE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; ENZYME INHIBITION; ENZYME MECHANISM; ENZYME SYNTHESIS; ORGANIC CHEMISTRY; REACTION TIME;

EID: 0030833253     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo970565m     Document Type: Article

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32. 3 (δ = 77.1) was used as the respective internal standard expressed in ppm. Column chromatography was performed on Merck kieselgel 60 (0.040-0.063 mm), and commercial kieselgel 60 F254 plates were used for thin layer chromatography. All solvents were distilled before use following usual procedures. Satisfactory analytical data (±0.3%) were obtained for all new compounds at theService Central d'Analyse du CNRS, Solaize, France.