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For reviews see interalia: Morris, J.H. Chem. Brit. 1991, 331-334. Hawthorne, M.F. Angew. Chem. 1993, 105, 997-1033 (Int. Ed Engl. 1993, 32, 950-984). Morin. C. Tetrahedron 1994, 50, 12521-12569. Lesnikowski, Z.J.; Schinazi, R.F. Polish. J. Chem. 1995, 69, 827-840. Barth, R.F.; Soloway, A.H.; Brugger, R.M. Cancer Invest. 1996, 14, 534-550.
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Stanko, V.I.; Anorova, G.A.; Klimova, T.V.; Klimova, T.P. Zh. Obshch. Khim . 1970, 40, 2432-2443 (Engl. Ed.: J. Gen. Chem. USSR , 1970, 40, 2418-2427). Malmquist, J.; Sjöberg, S. Tetrahedron 1996, 52, 9207-9218. Kahl, S.B.; Kasar, R.A. J. Am. Chem. Soc. 1996, 118, 1223-1224.
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Wade, K.5
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33
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0006154193
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Stanko, V.I.; Gol'tyapin, Y.V. Zh. Obshch. Khim. 1971, 41, 2033-2039 (Engl. Ed.: J. Gen. Chem. USSR , 1971, 41, 2053-2058).
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Stanko, V.I.1
Gol'tyapin, Y.V.2
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34
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0041961866
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Stanko, V.I.; Gol'tyapin, Y.V. Zh. Obshch. Khim. 1971, 41, 2033-2039 (Engl. Ed.: J. Gen. Chem. USSR , 1971, 41, 2053-2058).
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J. Gen. Chem. USSR
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-
-
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35
-
-
0343119730
-
-
1-Formyl-para-carborane has been prepared in several steps from 1 and has been used in C-C bond-forming processes : Stanko, V.I.; Brattsev, V.A.; Al'perovich, N.E. Zh. Obshch. Khim. 1970, 40, 1663 (Engl. Ed.: J. Gen. Chem. USSR , 1970, 40, 1652).
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Stanko, V.I.1
Brattsev, V.A.2
Al'perovich, N.E.3
-
36
-
-
0342685474
-
-
Engl. Ed.
-
1-Formyl-para-carborane has been prepared in several steps from 1 and has been used in C-C bond-forming processes : Stanko, V.I.; Brattsev, V.A.; Al'perovich, N.E. Zh. Obshch. Khim. 1970, 40, 1663 (Engl. Ed.: J. Gen. Chem. USSR , 1970, 40, 1652).
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J. Gen. Chem. USSR
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, pp. 1652
-
-
-
38
-
-
0343991770
-
-
note
-
2 then afforded 5 (8 %) m.p.=80°C (hexane); litt.(10): 80-81°C.
-
-
-
-
39
-
-
25344479128
-
-
To our knowledge, no C-boronic acid derivatives of carboranes have yet been described; for an attempt see: Boone, J.L.; Brotherton, R.J.; Petterson, L.L. Inorg. Chem. 1965, 4, 910-912.
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Inorg. Chem.
, vol.4
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-
Boone, J.L.1
Brotherton, R.J.2
Petterson, L.L.3
-
40
-
-
0343991769
-
-
8 % of 4 being recovered, this yield becomes 96 %, based on reacted material
-
8 % of 4 being recovered, this yield becomes 96 %, based on reacted material.
-
-
-
-
41
-
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0030576994
-
-
Malan, C.; Morin, C.; Preckher, G. Tetrahedron Lett. 1996, 37, 6705-6708.
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Malan, C.1
Morin, C.2
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42
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0006154769
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Zakharkin, L.I. Zhigareva, G.G. Zh. Obshch. Khim. 1970, 40, 2333-2334 (Engl. Ed.: J. Gen. Chem. USSR, 1970, 40, 2318). Zakharkin, L.I.; Zhigareva, G.G. Izsv. Akad Nauk. SSSR., Ser. Khim. 1970, 2290-2294 (Engl. Ed.: Bull. Acad. Sci. USSR, Chem. Ser. 1970, 2153-2156).
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Zakharkin, L.I.1
Zhigareva, G.G.2
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43
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0642355783
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Engl. Ed.
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Zakharkin, L.I. Zhigareva, G.G. Zh. Obshch. Khim. 1970, 40, 2333-2334 (Engl. Ed.: J. Gen. Chem. USSR, 1970, 40, 2318). Zakharkin, L.I.; Zhigareva, G.G. Izsv. Akad Nauk. SSSR., Ser. Khim. 1970, 2290-2294 (Engl. Ed.: Bull. Acad. Sci. USSR, Chem. Ser. 1970, 2153-2156).
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44
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0003492804
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Zakharkin, L.I. Zhigareva, G.G. Zh. Obshch. Khim. 1970, 40, 2333-2334 (Engl. Ed.: J. Gen. Chem. USSR, 1970, 40, 2318). Zakharkin, L.I.; Zhigareva, G.G. Izsv. Akad Nauk. SSSR., Ser. Khim. 1970, 2290-2294 (Engl. Ed.: Bull. Acad. Sci. USSR, Chem. Ser. 1970, 2153-2156).
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Izsv. Akad Nauk. SSSR., Ser. Khim.
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Zakharkin, L.I.1
Zhigareva, G.G.2
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45
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0343555658
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Engl. Ed.
-
Zakharkin, L.I. Zhigareva, G.G. Zh. Obshch. Khim. 1970, 40, 2333-2334 (Engl. Ed.: J. Gen. Chem. USSR, 1970, 40, 2318). Zakharkin, L.I.; Zhigareva, G.G. Izsv. Akad Nauk. SSSR., Ser. Khim. 1970, 2290-2294 (Engl. Ed.: Bull. Acad. Sci. USSR, Chem. Ser. 1970, 2153-2156).
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(1970)
Bull. Acad. Sci. USSR, Chem. Ser.
, pp. 2153-2156
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46
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33748793888
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-
Cookson, P.G.; Davies, A.G.; Fazzal, J.N. J. Organometal. Chem. 1985, 99, C31-C32. Taddei, M.; Ricci, A. Synthesis 1986, 633-635.
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Cookson, P.G.1
Davies, A.G.2
Fazzal, J.N.3
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47
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84986423122
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Cookson, P.G.; Davies, A.G.; Fazzal, J.N. J. Organometal. Chem. 1985, 99, C31-C32. Taddei, M.; Ricci, A. Synthesis 1986, 633-635.
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(1986)
Synthesis
, pp. 633-635
-
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Taddei, M.1
Ricci, A.2
-
48
-
-
0343991764
-
-
For B-hydroxy p-carboranes, see: Brattsev, V.A.; Stanko, V.I. Zh. Obshch. Khim. 1970, 40, 1664 (Engl. Ed.: J. Gen. Chem. USSR , 1970, 40, 1653). Stanko, V.I.; Brattsev, V.A.; Ovsyannikov, N.N.; Klimova, T.P. Zh. Obshch. Khim. 1974, 44, 2482-2489 (Engl. Ed.: J. Gen. Chem. USSR 1974, 44, 2441-2447).
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Zh. Obshch. Khim.
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, pp. 1664
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Brattsev, V.A.1
Stanko, V.I.2
-
49
-
-
0343555657
-
-
Engl. Ed.
-
For B-hydroxy p-carboranes, see: Brattsev, V.A.; Stanko, V.I. Zh. Obshch. Khim. 1970, 40, 1664 (Engl. Ed.: J. Gen. Chem. USSR , 1970, 40, 1653). Stanko, V.I.; Brattsev, V.A.; Ovsyannikov, N.N.; Klimova, T.P. Zh. Obshch. Khim. 1974, 44, 2482-2489 (Engl. Ed.: J. Gen. Chem. USSR 1974, 44, 2441-2447).
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(1970)
J. Gen. Chem. USSR
, vol.40
, pp. 1653
-
-
-
50
-
-
0242513191
-
-
For B-hydroxy p-carboranes, see: Brattsev, V.A.; Stanko, V.I. Zh. Obshch. Khim. 1970, 40, 1664 (Engl. Ed.: J. Gen. Chem. USSR , 1970, 40, 1653). Stanko, V.I.; Brattsev, V.A.; Ovsyannikov, N.N.; Klimova, T.P. Zh. Obshch. Khim. 1974, 44, 2482-2489 (Engl. Ed.: J. Gen. Chem. USSR 1974, 44, 2441-2447).
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(1974)
Zh. Obshch. Khim.
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, pp. 2482-2489
-
-
Stanko, V.I.1
Brattsev, V.A.2
Ovsyannikov, N.N.3
Klimova, T.P.4
-
51
-
-
0342685472
-
-
Engl. Ed.
-
For B-hydroxy p-carboranes, see: Brattsev, V.A.; Stanko, V.I. Zh. Obshch. Khim. 1970, 40, 1664 (Engl. Ed.: J. Gen. Chem. USSR , 1970, 40, 1653). Stanko, V.I.; Brattsev, V.A.; Ovsyannikov, N.N.; Klimova, T.P. Zh. Obshch. Khim. 1974, 44, 2482-2489 (Engl. Ed.: J. Gen. Chem. USSR 1974, 44, 2441-2447).
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(1974)
J. Gen. Chem. USSR
, vol.44
, pp. 2441-2447
-
-
-
54
-
-
0343555653
-
-
note
-
3): -14.0 (1 s); -16.2 (1 s).
-
-
-
-
55
-
-
0342685471
-
-
13C-NMR spectrum (δ=109.9) for the carborane carbon attached to oxygen is in agreement with those observed for ortho-carboranol derivatives, see : Morin, C.; Ramburrun, M. Curr. Topics Boron Chem., 1994, 228-231.
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(1994)
Curr. Topics Boron Chem.
, pp. 228-231
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Morin, C.1
Ramburrun, M.2
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