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Volumn 38, Issue 37, 1997, Pages 6599-6602

Synthesis of unsymmetrical C-disubstituted para-Carboranes: Access to functionalized carboranyl-boronic acid and carboranol

Author keywords

[No Author keywords available]

Indexed keywords

BORONIC ACID DERIVATIVE; CARBORANE DERIVATIVE;

EID: 0030821572     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(97)01510-4     Document Type: Article
Times cited : (17)

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    • 1-Formyl-para-carborane has been prepared in several steps from 1 and has been used in C-C bond-forming processes : Stanko, V.I.; Brattsev, V.A.; Al'perovich, N.E. Zh. Obshch. Khim. 1970, 40, 1663 (Engl. Ed.: J. Gen. Chem. USSR , 1970, 40, 1652).
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    • 8 % of 4 being recovered, this yield becomes 96 %, based on reacted material
    • 8 % of 4 being recovered, this yield becomes 96 %, based on reacted material.
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    • For B-hydroxy p-carboranes, see: Brattsev, V.A.; Stanko, V.I. Zh. Obshch. Khim. 1970, 40, 1664 (Engl. Ed.: J. Gen. Chem. USSR , 1970, 40, 1653). Stanko, V.I.; Brattsev, V.A.; Ovsyannikov, N.N.; Klimova, T.P. Zh. Obshch. Khim. 1974, 44, 2482-2489 (Engl. Ed.: J. Gen. Chem. USSR 1974, 44, 2441-2447).
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    • For B-hydroxy p-carboranes, see: Brattsev, V.A.; Stanko, V.I. Zh. Obshch. Khim. 1970, 40, 1664 (Engl. Ed.: J. Gen. Chem. USSR , 1970, 40, 1653). Stanko, V.I.; Brattsev, V.A.; Ovsyannikov, N.N.; Klimova, T.P. Zh. Obshch. Khim. 1974, 44, 2482-2489 (Engl. Ed.: J. Gen. Chem. USSR 1974, 44, 2441-2447).
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    • For B-hydroxy p-carboranes, see: Brattsev, V.A.; Stanko, V.I. Zh. Obshch. Khim. 1970, 40, 1664 (Engl. Ed.: J. Gen. Chem. USSR , 1970, 40, 1653). Stanko, V.I.; Brattsev, V.A.; Ovsyannikov, N.N.; Klimova, T.P. Zh. Obshch. Khim. 1974, 44, 2482-2489 (Engl. Ed.: J. Gen. Chem. USSR 1974, 44, 2441-2447).
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    • For B-hydroxy p-carboranes, see: Brattsev, V.A.; Stanko, V.I. Zh. Obshch. Khim. 1970, 40, 1664 (Engl. Ed.: J. Gen. Chem. USSR , 1970, 40, 1653). Stanko, V.I.; Brattsev, V.A.; Ovsyannikov, N.N.; Klimova, T.P. Zh. Obshch. Khim. 1974, 44, 2482-2489 (Engl. Ed.: J. Gen. Chem. USSR 1974, 44, 2441-2447).
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    • note
    • 3): -14.0 (1 s); -16.2 (1 s).
  • 55
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    • 13C-NMR spectrum (δ=109.9) for the carborane carbon attached to oxygen is in agreement with those observed for ortho-carboranol derivatives, see : Morin, C.; Ramburrun, M. Curr. Topics Boron Chem., 1994, 228-231.
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