X-ray Structure of [Ru(bpy)3]0: An Expanded Atom or a New Electride?

Angewandte Chemie (International Edition in English)

Volumn 36, Issue 1-2, 1997, Pages 137-140

  Pérez Cordero, Eduardo E ^a   Campana, Charles ^b   Echegoyen, Luis ^a  

^a Department of Biology   (United States)

^b Siemens Energy and Automation Inc   (United States)

Author keywords

Electrocrystallization; Electronic structure; N ligands; Ruthenium

Indexed keywords

EID: 0030812324     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199701371     Document Type: Article

References (24)

1. E. Pérez-Cordero, R. Buigas, N. Brady, L. Echegoyen, C. Arana, J.-M. Lehn, Helv. Chim. Acta 1994, 77, 1222.
2. a) D. E. Morris, K. W, Hanck, M. K. DeArmond, Inorg. Chem. 1985, 24, 977;
3. b) J. Am. Chem. Soc. 1983, 105, 3032;
4. c) A. G. Motten, K. W, Hanck, M. K. DeArmond, Chem. Phys. Lett. 1981, 79, 541.
5. M. J. Wagner, J. L. Dye, E. Pérez-Cordero, R. Buigas, L. Echegoyen, J. Am. Chem. Soc. 1995, 117, 1318.
6. L, Echegoyen, A. DeCian, J. Fischer, J.-M. Lehn. Angew. Chem. 1991, 103, 884; Angew. Chem. Int. Ed. Engl. 1991, 30, 838.
7. L, Echegoyen, A. DeCian, J. Fischer, J.-M. Lehn. Angew. Chem. 1991, 103, 884; Angew. Chem. Int. Ed. Engl. 1991, 30, 838.
8. Y. Ohsawa, M.-H. Whangbo, K. W. Hanck, M. K. DeArmond. Inorg. Chem. 1984, 23. 3426.
9. T. Suzuki, Y. Maruyama, T. Kato, T. Akasaka, K. Kohayashi, S. Nuguse, K. Yamamoto, H. Funasaka, T. Takahashi, J Am. Chem. Soc. 1995, 117, 9606.
10. a) M. Biner, H.-B. Bürgi, A. Ludi, C. Röhr. J. Am. Chem. Soc. 1992, 114, 5197;
11. b) H. Tamura, N. Ikeda, T. Iguro, T. Ohno. G.-E. Matsubayashi. Acta Crystallogr. Sect. C 1996, 52, 1394.
12. 0)/3) for 1993 observations and 181 parameters (hydrogen atoms in calculated positions. d(C-H) = 0.95 Å).
13. Siemens Industrial Automation, Inc. 6300 Enterprise Lane, Mudison, WJ 53719 (USA)
14. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Cristallographic Data Centre as supplementary publication no. CCDC-179-136. Copies of the data can be obtained free of charge on application to The Director. CCDC, 12 Union Road, Cambridge CB2 1EZ, UK deposit@chemcrys.cam.ac.uk.
15. a) W. L. Jorgensen, D. L. Severance, J. Am. Chem. Soc. 1990, 112, 4768;
16. b) S. Paliwal, S. Geib, C. S. Wilcox, ibid. 1994, 116, 4497:
17. c) K. Miyamura, A. Mihara, T. Fujii, Y. Gohshi, Y. Ishii, ibid. 1995, 117, 2377;
18. d) H. Adams, F. J. Carver, C. A. Hunter, J. C. Morales, E. M. Seward, Angew. Chem. 1996, 108, 1628; Angew. Chem. Int. Ed. Engl. 1996, 35, 1542.
19. d) H. Adams, F. J. Carver, C. A. Hunter, J. C. Morales, E. M. Seward, Angew. Chem. 1996, 108, 1628; Angew. Chem. Int. Ed. Engl. 1996, 35, 1542.
20. Y. Ohsawa. M. K. DeArmond. K. W. Hanck, D, E. Morris, J. Am. Chem. Soc. 1983. 105, 6522.
21. E. Pérez-Cordero, N. Brady, L. Echegoyen, R. Thummel, C.-Y Hung, S. G. Bott, Chem. Eur-. J. 1996, 2, 781.
22. a) J. L. Dye. Chemtracts-Inorg. Chem. 1993, 5, 243;
23. b) M. J. Wagner. J. L. Dye, Annu. Rev. Maler. Sci. 1993, 23, 223.
24. J. L. Dye, M. J. Wagner, G. Overney, R. H. Huang, T. F. Nagy, D. Tománek, J. Am. Chem. Soc. 1996, 118, 7329.