Stereoselective Synthesis and Isomerization of η1-2-Phosphabutadiene Complexes to η1-2,3-Dihydrophosphete Complexes

Angewandte Chemie (International Edition in English)

Volumn 36, Issue 10, 1997, Pages 1095-1097

  Streubel, Rainer ^a   Hobbold, Markus ^a   Jeske, Jörg ^a   Jones, Peter G ^a  

^a TECHNICAL UNIVERSITY OF BRAUNSCHWEIG   (Germany)

Author keywords

Carbene complexes; Phosphorus heterocycles; Valence isomerization

Indexed keywords

EID: 0030808353     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199710951     Document Type: Article

References (18)

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11. Until now the 2,3-dihydrophosphete ring was only known as a subunit of 2-Dewar-phosphinines: J. Fink, W. Rösch, U.-J. Vogelbacher, M. Regitz, Angew. Chem. 1986, 98, 265; Angew. Chem. Int. Ed. Engl. 1986, 25, 280.
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14. -3. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-100026. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: int. code + (1223)336-033: e-mail: deposit@chemcrys.cam.ac.uk).
15. It has been assumed that the configuration at the C-C double bond is determined at the stage of the metallaallyl anion or vinylmetallate: C. P. Casey, W. R. Brunsvold, Inorg. Chem. 1977, 16, 391.
16. Theoretical studies of the structure and reductive elimination of complexes with seven-coordinate metal centers: R. Hoffmann, B. F. Beier, E. L. Muetterties, A. R. Rossi, Inorg. Chem. 1977, 16, 511.
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