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Volumn 119, Issue 35, 1997, Pages 8191-8200

The ratio between endocyclic and exocyclic cleavage of pyranoside acetals is dependent upon the anomer, the temperature, the aglycon group, and the solvent

Author keywords

[No Author keywords available]

Indexed keywords

ACETAL DERIVATIVE; PYRANOSIDE; SOLVENT;

EID: 0030799390     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja963807t     Document Type: Article
Times cited : (30)

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    • note
    • In our original communication describing the experimental design using 1, we reported 14% endocyclic cleavage at 25°C. As can be seen by analysis of Table 1, 10% endocyclic cleavage would be predicted from extrapolation to 25°C.
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