An ab initio computational molecular orbital study of radical, protonated radical (radical cation), and carbocation species that have been proposed in mechanisms for the transfer process in the enzyme - Coenzyme B12-catalyzed dehydration of 1,2-dihydroxyethane

Journal of the American Chemical Society

Volumn 119, Issue 30, 1997, Pages 7065-7074

  George, Philip ^a,b   Glusker, Jenny P ^a   Bock, Charles W ^c  

^a FOX CHASE CANCER CENTER   (United States)

^b UNIVERSITY OF PENNSYLVANIA   (United States)

^c THOMAS JEFFERSON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; CATION; COBAMAMIDE; ETHYLENE DERIVATIVE;

ARTICLE; DEHYDRATION; ENZYME ACTIVE SITE; ENZYME ACTIVITY; ENZYME KINETICS; HYDROPHOBICITY;

EID: 0030793223     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja963424v     Document Type: Article

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