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85033153964
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note
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When the reaction was carried out using larger quantities, the yield of isolated product decreased drastically, probably due to decomposition of the product during chromatography. Attempts to improve the yield of the reaction on a multigram scale, viz. by distillation of the reaction mixture or acid-base extraction, were not successful.
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22
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85033147432
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The product isolated after the rearrangement gave the same optical rotation as the one obtained initially from the phosphorylation reaction
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The product isolated after the rearrangement gave the same optical rotation as the one obtained initially from the phosphorylation reaction.
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23
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28
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85033157079
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A crude yield of ca. 90% was obtained. However, during the chromatographic procedure a considerable portion of the product was irriversibly bound to the silica
-
A crude yield of ca. 90% was obtained. However, during the chromatographic procedure a considerable portion of the product was irriversibly bound to the silica.
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29
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1542558628
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Sommerdijk, N. A. J. M.; Buijnsters, P. J. J. A.; Pistorius, A. M. A.; Wang, M.; Feiters, M. C.; Nolte, R. J. M.; Zwanenburg, B. J. Chem. Soc., Chem. Commun. 1994, 1941; 1994, 2739.
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30
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1542558627
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