Separation of faradaic and capacitive current regions in the redox transformation of poly(3-methylthiophene) with the exclusion of overoxidation processes

Electrochimica Acta

Volumn 42, Issue 4, 1997, Pages 651-657

  Visy, Cs ^a   Lakatos, M ^a   Szücs, Á ^a   Novak M ^a  

^a UNIVERSITY OF SZEGED   (Hungary)

Author keywords

Electronically conducting polymer; Faradaic capacitive current; Poly(3 methylthiophene); Redox transformation

Indexed keywords

CAPACITANCE; CONDUCTIVE PLASTICS; ELECTRIC CURRENTS; ORGANIC SOLVENTS; OXIDATION; REDOX REACTIONS; SUPERCONDUCTING FILMS;

CAPACITIVE CURRENT; FARADAIC CURRENT; NITROBENZENE; REDOX TRANSFORMATION;

PLASTIC FILMS;

EID: 0030790557     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0013-4686(96)00210-1     Document Type: Article

References (31)

1. A. F. Diaz and J. I. Castillo, J Chem. Soc. Chem. Commun. 397 (1980).
2. A. F. Diaz, J. I. Castillo, J. A. Logan and W. Y. Lee, J Electroanal. Chem. 129, 115 (1981).
3. S. W. Feldberg, J. Am. Chem. Soc. 106, 4671 (1984).
4. I. Rubinstein, E. Sabatani and J. Rishpon, J. Electrochem. Soc. 134, 3078 (1987).
5. J. Heinze, J. Mortensen, K. Mullen and R. Schenk, J. Chem. Soc. Chem. Commun. 701 (1987).
6. W. J. Albery, Z. Chen, B. R Horrocks, A. R. Mount, P. J. Wilson, D. Bloor, A. T. Monkman and C. M. Elliot, Faraday Discuss. Chem. Soc. 88, 247 (1989).
7. R. S. Hutton, M. Kalaji and L. M. Peter, J. Electroanal. Chem. 270, 429 (1989).
8. J. Tanguy, J. L. Baudoin, G. Chao and M. Costa, Electrochem. Acta 37, 1417 (1992).
9. P. Bäuerle, Adv. Mater. 4, 102 (1992).
10. J. Roncali, P. Marque, R. Garreau, F. Gamier and M. Lemaire, Macromolecules 23, 1347 (1990).
11. P. A. Christensen and A. Hamnett, Techniques and Mechanisms in Electrochemistry, p. 335. Blackie Academic & Professional, London (1994).
12. G. Zotti, G. Schiavon, A. Berlin and G. Pagani, Synth. Metals 61, 81 (1993).
13. G. S. Popkirov and E. Barsoukov, J. Electroanal. Chem. 383, 155 (1995).
14. H. Harada, T. Fuchigami and T. Nonaka, J. Electroanal. Chem. 303, 139 (1991).
15. Z. Gao, M. Zi and B. Chen, J. Electroanal. Chem. 373, 141 (1994).
16. A. A. Pud, Synth. Metals 66, 1 (1994).
17. Cs. Visy, J. Lukkari and J. Kankare, J. Electroanal. Chem. 401, 119 (1996).
18. E. W. Tsai, S. Basak, J. P. Ruiz, J. R. Reynolds and K. Rajeshwar, J. Electrochem. Soc. 136, 3683 (1989).
19. A. O. Patil, A. J. Heeger and F. Wudl, Chem. Rev. 183 (1988).
20. Cs. Visy, J. Lukkari and J. Kankare, J. Electroanal. Chem. 319, 85 (1991).
21. Cs. Visy, J. Lukkari and J. Kankare, Macromolecules 26, 3295 (1993).
22. Cs. Visy, J. Lukkari and J. Kankare, Macromolecules 27, 3322 (1994).
23. J. Roncali, A. Yassar and F. Garnier, J. Chem. Soc. Chem. Commun. 581 (1988).
24. M.-N. Collomb-Dunard-Sauthier, S. Langlois and E. Genies, J. Appl. Electrochem. 24, 72 (1994).
25. M. Costa, F. Chao, E. Museux and C. Tian, J. Chim. Phys., Phys.-Chim. Biol. 92, 939 (1995).
26. T. F. Otero, J. Rodriguez, E. Angulo and C. Santamaria, Synth. Met. 57, 3713 (1993).
27. Q. Pei and O. Inganäs, Synth. Met. 57, 3718 (1993).
28. X. Chen and O. Inganäs, Synth. Metals 74, 159 (1995).
29. A. Hamnett and A. R. Hillmann, Ber. Bunsenges. Phys. Chem. 91, 329 (1987).
30. J. R. Wyhof and H. A. Pohl, J. Polym. Sci. A 8, 1741 (1970).
31. C. Arbizzani, M. Mastragostino and L. Meneghello, Electrochim. Acta 41, 21 (1996).