Molecular Self-Assembly to Give the Antiferromagnetic Cage Compound [{CpFe(CO)2(Mes)PO2}4{MesPO3Fe 2(OH)Cl}2]

Angewandte Chemie (International Edition in English)

Volumn 36, Issue 1-2, 1997, Pages 55-56

  Lorenz, Ingo Peter ^a   Pohl, Wolfgang ^a   Nöth, Heinrich ^a  

^a Inst Anorganische Chem Univ M   (Germany)

Author keywords

Cage compounds; Iron; Magnetic properties; P ligands; Self assembly

Indexed keywords

EID: 0030786947     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199700551     Document Type: Article

References (11)

1. A. Müller, K. Hovemeier, E. Krickemeyer, H. Böcke, Angew. Chem. 1995, 107, 856; Angew. Chem. Int. Ed. Engl. 1995, 34, 779; further examples for molecular self-assembly can be found in J.-M. Lehn, Supermolecular Chemistry: Concepts and Perspectives, VCH, New York, 1995.
2. A. Müller, K. Hovemeier, E. Krickemeyer, H. Böcke, Angew. Chem. 1995, 107, 856; Angew. Chem. Int. Ed. Engl. 1995, 34, 779; further examples for molecular self-assembly can be found in J.-M. Lehn, Supermolecular Chemistry: Concepts and Perspectives, VCH, New York, 1995.
3. A. Müller, K. Hovemeier, E. Krickemeyer, H. Böcke, Angew. Chem. 1995, 107, 856; Angew. Chem. Int. Ed. Engl. 1995, 34, 779; further examples for molecular self-assembly can be found in J.-M. Lehn, Supermolecular Chemistry: Concepts and Perspectives, VCH, New York, 1995.
4. a) W. Pohl, I.-P. Lorenz, H. Nöth, M. Schmidt, Z. Naturforsch. B 1995, 50, 1485;
5. b) I.-P. Lorenz, P. Mürschel, W. Pohl, K. Polborn, Chem. Ber. 1995, 128, 441;
6. I.-P. Lorenz, W. Pohl, K. Polborn, ibid. 1996, 129, 11.
7. I.-P. Lorenz, W. Pohl, H. Nöth, M. Schmidt, J. Organomet. Chem. 1994, 475, 211.
8. W. Pohl, PhD Thesis , University of München, 1995.
9. Kα (λ = 0.71073 Å), T = 213 K, 2θ = 3.24-47.00, ω scan, scan range (ω) 1.2°, reflections; 5241 measured, 4967 of which were independent (R(int) = 0.1251), 3022 observed [F>4σ(F)]. The structure was solved with the programs XS (Siemens) and SHELXL (G. M. Sheldrick, Göttingen, 1993) by direct methods and refined by full-matrix least squares refinement. The hydrogen atoms were refined as riding atoms with fixed isotropic temperature parameters. 553 refined parameters, R = 0.0693, wR2 = 0.1308, GOOF = 1.049. Further details of the crystal structure investigation may be obtained from the Fachinformationszentrum Karlsruhe, D-76344 Eggenstein-Leopoldshafen (Germany), on quoting the depository number CSD-405885.
10. 3CN per molecule of 2.
11. J.-P. Lorenz, K. Thurow, J. Organomet. Chem. 1995, 496, 191.