[Cp2ZrHCl](n) A useful reducing agent in phosphorus chemistry

Tetrahedron Letters

Volumn 38, Issue 34, 1997, Pages 5997-6000

  Zablocka, Maria ^a   Delest, Bruno ^b   Igau, Alain ^b   Skowronska, Aleksandra ^a   Majoral, Jean Pierre ^b  

^a CENTRE OF MOLECULAR AND MACROMOLECULAR STUDIES   (Poland)

^b LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ORGANOPHOSPHORUS COMPOUND; PHOSPHINE DERIVATIVE;

ARTICLE; DRUG SYNTHESIS; IN VITRO STUDY; METHODOLOGY; REACTION ANALYSIS; REDUCTION;

EID: 0030785756     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(97)01365-8     Document Type: Article

References (7)

1. Gilheany, D. G.; Mitchell, C. M. The Chemistry of Organophosphorus Compounds, Edit. Hartley, F. R., John Wiley & Sons Ltd, 1990, vol. 1, pp 152-190.
2. Labinger, J. A. Comprehensive Organic Synthesis; Pergamon Press, Oxford, England 1991, vol. 8, pp 667-402.
3. Experimental conditions for the reduction of 2-4: 4 h at 40°C then 48 h at 22°C in THF for 2; 14 h at 55°C in THF (55% yield) for 3; 20 h at 50°C in THF for 4.
4. 13C NMR, mass spectrometry and elemental analysis.
5. Zablocka, M.; Igau, A.; Cénac, N.; Donnadieu, B.; Dahan, F.; Majoral, J.-P.; Pietrusiewicz, K. M. J. Am. Chem. Soc. 1995, 117, 8083-808.
6. Zablocka, M.; Igau, A.; Majoral, J.-P.; Pietrusiewicz, K. M. Organometallics 1993, 12, 603-604.
7. Cénac, N.; Zablocka, M.; Igau, A.; Majoral, J.-P.; Skowronska, A. J. Org. Chem. 1996, 61, 796-798.