SIMS analysis of oxygen isotopes: Matrix effects in complex minerals and glasses

Chemical Geology

Volumn 138, Issue 3-4, 1997, Pages 221-244

  Eiler, John M ^a   Graham, Colin ^b   Valley, John W ^c  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^b UNIVERSITY OF EDINBURGH   (United Kingdom)

^c UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

Ion microprobe; Matrix effects; Oxygen isotopes; Standards

Indexed keywords

INSTRUMENTAL MASS FRACTIONATION; MATRIX EFFECT; OXYGEN ISOTOPE; SIMS;

EID: 0030783333     PISSN: 00092541     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0009-2541(97)00015-6     Document Type: Article

References (43)

1. 18O content of standard mean ocean water. Earth Planet. Sci. Lett. 31, 341-344.
2. Dean, J.A. (Editor), 1985. Lange's Handbook of Chemistry, 13th ed. McGraw Hill, New York.
3. Deline, V.R., Katz, W., Evans, C.A., Williams, P., 1978. Mechanism of the SIMS matrix effect. Appl. Phys. Lett. 33, 832-835.
4. Deloule, E., France-Lanord, C., Albarède, F., 1991. D/H analysis of minerals by ion probe. In: H.P. Taylor, Jr., J.R. O'Neil and I.R. Kaplan (Editors), Stable Isotope Geochemistry: A Tribute to Samuel Epstein. Geochem. Soc. Spec. Publ. 3, 53-62.
5. Eiler, J.M., Valley, J.W., Graham, C.M., Baumgartner, L.P., 1995. Ion microprobe evidence for the mechanisms of stable isotope retrogression in high-grade metamorphic rocks. Contrib. Mineral. Petrol. 118, 365-378.
6. Eiler, J.M., Valley, J.W., Graham, C.M., 1997. Standardization of SIMS Analysis Of O and C isotope ratios in Carbonates from ALH-84001. 28th Lunar and Planetary Science Conference, in press.
7. Elsenheimer, D., Valley, J.W., 1992. In situ oxygen isotope analysis of feldspar and quartz by Nd:YAG laser microprobe. Chem. Geol. 101, 21-42.
8. Engstrom, E.U., Lodding, A., Odelius, H., Sodervall, U., 1987. SIMS yields from glasses; secondary ion energy dependence and mass fractionation. Mikrochim. Acta 1, 387-400.
9. Farqhar, J., Chacko, T., Frost, R.B., 1993. Strategies for high-temperature oxygen isotope thermometry; a worked example from the Laramie anorthosite complex, Wyoming, USA. Earth Planet. Sci. Lett. 117, 407-422.
10. Gerhard, W. and Plog, C., 1987. SIMS-matrix effect and model of ion pair production (Part II). In: A. Benninghoven, A.M. Huber and H.W. Werner (Editors), SIMS VI. John Wiley, Chichester, pp. 109-112.
11. Giletti, B.J., Shimizu, B., 1989. Use of the ion microprobe to measure natural abundances of oxygen isotopes in minerals. In: W.C. Shanks III and R.E. Criss, New Frontiers in Stable Isotope Research. U.S. Geol. Surv. Bull. 1890, 129-136.
12. Gnaser, H., Hutcheon, I.D., 1987. Velocity dependent isotope fractionation in secondary ion emission. Phys. Rev. B35, 877-879.
13. 16O in authigenic and detrital quartz in the St. Peter Sandstone, Michigan Basin and Wisconsin Arch, USA: contrasting diagenetic histories. Geochim. Cosmochim. Acta 60, 5101-5116.
14. Hervig, R.L., Williams, P., Thomas, R.M., Schauer, S.N., Steele, I.M., 1992. Microanalysis of oxygen isotopes in insulators by secondary ion mass spectrometry. Int. J. Mass Spectrom. Ion Process. 120, 45-63.
15. Jamtveit, B., Hervig, R.L., 1994. Constraints on transport and kinetics in hydrothermal systems from zoned garnet crystals. Nature 263, 505-508.
16. Leshin, L.A., Rubin, A.E., McKeegan, K.D., 1996. Oxygen isotopic compositions of olivine and pyroxene from CI chondrites. Lunar Planet. Sci. 27, 745-746.
17. Lorin, J.C., Slodzian, R., Dennebouy, R. and Chaintreau, M., 1990. SIMS measurement of oxygen isotope-ratios in meteorites and primitive solar matter. In: A. Benninghoven, C.A. Evans, K.D. McKeegan, H.A. Storms and H.W. Werner (Editors), Secondary Ion Mass Spectrometry, SIMS VII. John Wiley, Chichester, pp. 377-380.
18. Lyon, I.C., Saxton, J.M., Turner, G., 1994. Isotopic fractionation in secondary ionization mass spectrometry. Rapid Commun. Mass Spectrom. 8, 837-843.
19. Mattey, D., Macpherson, C.M., 1993. High-precision oxygen isotope analysis of microgram quantities of silicate by laser-fluorination. Chem. Geol. 105, 305-318.
20. McKeegan, K.D., 1987. Oxygen isotopes in refractory stratospheric dust particles: proof of extraterrestrial origin. Science 237, 1468-1471.
21. Ricci, M.P., Merritt, D.A., Freeman, K.H., Hayes, J.M., 1994. Acquisition and processing of data for isotope-ratio-monitoring mass spectrometry. Org. Geochem. 21, 561-571.
22. Riciputi, L.R., Paterson, B.A., 1994. High spatial resolution measurement of O isotope ratios in silicates and carbonates by ion microprobe. Am. Mineral. 79, 1227-1230.
23. 16O ratios in chemically-zoned silicates by ion microprobe: an empirical method. Submitted to Geochim. Cosmochim. Acta.
24. Santos, R.V., Clayton, R.N., 1995. Variations in oxygen and carbon isotopes in carbonatites: a study of Brazilian alkaline complexes. Geochim. Cosmochim. Acta 59, 1339-1352.
25. Schauer, S.N., Williams, P., 1990. Elimination of cluster interferences in secondary ion mass spectrometry using extreme energy filtering. Int. J. Mass Spectrom. Ion Process. 103, 21-29.
26. Schauer, S.N., Williams, P., Hervig, R., Lareau, R.T., 1993. Energy dependent mass fractionation of ions during sputtering. SIMS 9, 64-67.
27. Sharp, Z.D., 1990. A laser based microanalytical method for the in situ determination of oxygen isotope ratios in silicates and oxides. Geochim. Cosmochim. Acta 54, 1353-1357.
28. Sharp, Z.D., Cerling, T.E., 1995. A laser GC-IRMS method for in situ carbon and oxygen isotope analysis of carbonates and phosphates. Geol. Soc. Am. Abstr. Prog. A 255.
29. Shimizu, N., Hart, S.R., 1982. Applications of the ion microprobe to geochemistry and cosmochemistry. Annu. Rev. Earth Planet. Sci. 10, 483-526.
30. Shroeer, J.M., Rhodin, T.N., Bradley, R.C., 1973. A quantum-mechanical model for the ionization and excitation of atoms during sputtering. Surface Sci. 34, 571-580.
31. Sigmund, P., 1969. Theory of sputtering, I. Sputtering yield of amorphous and polycrystalline targets. Phys. Rev. 184, 383-416.
32. Slodzian, G., Lorin, J.C., Havette, A., 1980. Isotopic effect on the ionization probabilities in secondary ion emission. J. Phys. 41, L555-L558.
33. Thompson, M.W., 1968. II. The energy spectrum of ejected atoms during the high energy sputtering of gold. Philos. Mag. 18, 377-414.
34. Valley, J.W., Graham, C.M., 1991. Ion microprobe analysis of oxygen isotope ratios in granulite facies magnetites: diffusive exchange as a guide to cooling history. Contrib. Mineral. Petrol. 109, 38-52.
35. Valley, J.W., Graham, C.M., 1996. Ion microprobe analysis of oxygen isotope ratios in quartz from Skye granite: healed micro-cracks, fluid flow, and hydrothermal exchange. Contrib. Mineral. Petrol. 124, 225-234.
36. Valley, J.W., Kitchen, N., Kohn, M.J., Niendorf, C.R., Spicuzza, M.J., 1995. UWG-2, a garnet standard for oxygen isotope ratio: strategies for high precision and accuracy with laser heating. Geochim. Cosmochim. Acta 59, 5223-5231.
37. Valley, J.W., Graham, C.M., Harte, B., Eiler, J.M., Kinny, P.D., 1997a. Ion microprobe analysis of oxygen, carbon and hydrogen isotope ratios. In: M.A. McKibben and W.C. Shanks (Editors), Applications of Microanalytical Techniques to Understanding Mineralizing Processes, Vol. 7, in press.
38. Valley, J.W., Kinny, P.D., Schulz, D.J. and Spicuzza, M.J., 1997b. Zircon megacrysts from kimberlite: O isotope heterogeneity in the mantle. Science, submitted.
39. 100Mo targets. Nucl. Instrum. Methods, B 73, 135-150.
40. Wiechert, U., Hoefs, J., 1995. An excimer laser-based micro analytical preparation technique for in situ oxygen isotope analysis of silicate and oxide minerals. Geochim. Cosmochim. Acta 59, 4093-4101.
41. Williams, P., 1979. The sputtering process and sputtered ion emission. Surf. Sci. 90, 588-643.
42. Yu, M.L., Lang, N., 1986. Mechanisms of atomic ion emission during sputtering. Nucl. Instrum. Methods B14, 403-413.
43. Yurimoto, H., Nagasawa, H., Mori, Y., Matsubaya, O., 1994. Micro-distribution of oxygen isotopes in a refractory inclusion from the Allende meteorite. Earth Planet. Sci. Lett. 128, 47-53.