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85088079713
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note
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1H NMR NOESY experiment showing, for example, a strong cross-peak correlation between the H-5 naphtholic hydrogen and the H-4 olefinic hydrogen in compound 5fx.
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28
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35
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note
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It is important to emphasize that the rearrangement of aryl propargyl ethers requires high temperatures (220-240°C), whereas the present reaction occurs at 130°C.
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