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85033152460
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85033156936
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85033135439
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note
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2, see Ref. 4b, the triplet decay time KCD-J and KCD-DA, 10-15 μs, in a PMMA film because more than 50 μs by applying an oxygen barrier layer on the sample, suggesting that the triplet in a PMMA film was quenched by oxygen which penetrated into the film. Since the xenon lamp pulse for monitor light was about 100 μs, it was too short to analyse the triplet decay in the PMMA film sample with an oxygen barrier layer.
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23
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85033147829
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note
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q) remarkably reduced with ΔG higher than 0 eV, and almost reached to the diffusion controlled rate with AG lower than -0.867 eV. The fact supports the possibility of the electron-transfer quenching of the dyes by BI with the threshold of ΔG.
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24
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85033129724
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note
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As for the curve fitting for KCD-J in the presence of BI, we ignored the increase of base line due to the unknown transient product, which was formed from singlet sensitized decomposition of BI, because of the low absorption of the product less than 10% of total transient absorption at 600 nm.
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26
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85033142649
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note
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00 is the excitation energy of the ketocoumarin singlets and triplets, and C, coulombic term, usually assumed to value ca. 0.1 eV for acetonitrile solvent.
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27
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85011120982
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85033134758
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note
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7a)
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29
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85033143240
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