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Volumn 119, Issue 28, 1997, Pages 6575-6582

Large molecular hyperpolarizabilities. Quantitative analysis of aromaticity and auxiliary donor-acceptor effects

Author keywords

[No Author keywords available]

Indexed keywords

1,2,3 TRIAZINE; 1,2,4,5 TETRAZINE; AROMATIC COMPOUND; FURAN; PYRAZINE; PYRIDAZINE; PYRIDINE; PYRROLE; THIOPHENE; UNCLASSIFIED DRUG;

EID: 0030751327     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja962968u     Document Type: Article
Times cited : (397)

References (64)
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    • Polymers for Second Order Nonlinear Optics
    • American Chemical Society Washington, DC
    • (a) Polymers for Second Order Nonlinear Optics; Lindsay, G. A., Singer K. D., Eds.; ACS Symposium Series Vol. 601; American Chemical Society Washington, DC, 1995.
    • (1995) ACS Symposium Series , vol.601
    • Lindsay, G.A.1    Singer, K.D.2
  • 16
    • 5944242890 scopus 로고
    • (b) Clays, K.; Persoons, A. Phys. Rev. Lett. 1991, 66, 2980; Adv. Chem. Phys. 1994, 85, 455.
    • (1994) Adv. Chem. Phys. , vol.85 , pp. 455
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    • 1842324497 scopus 로고
    • Polymers for Second Order Nonlinear Optics; Lindsay, G. A., Singer, K. D., Eds.; American Chemical Society: Washington, DC
    • (a) Jen, A. K-Y.; Rao, V. P.; Chandrasekhar, J. In Polymers for Second Order Nonlinear Optics; Lindsay, G. A., Singer, K. D., Eds.; ACS Symposium Series 601; American Chemical Society: Washington, DC, 1995.
    • (1995) ACS Symposium Series , vol.601
    • Jen, A.K.-Y.1    Rao, V.P.2    Chandrasekhar, J.3
  • 48
    • 1842320661 scopus 로고    scopus 로고
    • note
    • 20c to account for the resistance to the circulation of electrons about the rings by the presence of electronegative atoms such as N, O, etc. in heterocycles. That is atoms with higher electronegativity will exhibit higher resistance to electron flow (ring currents) and hence should lead to a smaller aromaticity. This resistance has been shown to be proportional to the charge gradient, the second term in eq 1.
  • 56
    • 0037936224 scopus 로고
    • (a) Albert, I. D. L.; Morley, J. O.; Pugh, D. J. Chem. Phys. 1993, 99, 5197; 1995, 102, 237.
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  • 62
    • 1842317784 scopus 로고
    • Polymers for Second-Order Nonlinear Optics; Lindsay, G. A., Singer, K. D., Eds.; American Chemical Society: Washington, DC
    • Albert, I. D. L.; Di Bella, S.; Kanis, D. R.; Marks, T. J.; Ratner, M. A. In Polymers for Second-Order Nonlinear Optics; Lindsay, G. A., Singer, K. D., Eds.; ACS Symposium Series Vol. 601; American Chemical Society: Washington, DC, 1995. Di Bella, S.; Marks, T. J.; Ratner, M. A. J. Am. Chem. Soc. 1994, 116, 4440. Yu, J.; Zerner, M. C. J. Chem. Phys. 1994, 100, 7487.
    • (1995) ACS Symposium Series , vol.601
    • Albert, I.D.L.1    Di Bella, S.2    Kanis, D.R.3    Marks, T.J.4    Ratner, M.A.5
  • 63
    • 0001564855 scopus 로고
    • Albert, I. D. L.; Di Bella, S.; Kanis, D. R.; Marks, T. J.; Ratner, M. A. In Polymers for Second-Order Nonlinear Optics; Lindsay, G. A., Singer, K. D., Eds.; ACS Symposium Series Vol. 601; American Chemical Society: Washington, DC, 1995. Di Bella, S.; Marks, T. J.; Ratner, M. A. J. Am. Chem. Soc. 1994, 116, 4440. Yu, J.; Zerner, M. C. J. Chem. Phys. 1994, 100, 7487.
    • (1994) J. Am. Chem. Soc. , vol.116 , pp. 4440
    • Di Bella, S.1    Marks, T.J.2    Ratner, M.A.3
  • 64
    • 36449005773 scopus 로고
    • Albert, I. D. L.; Di Bella, S.; Kanis, D. R.; Marks, T. J.; Ratner, M. A. In Polymers for Second-Order Nonlinear Optics; Lindsay, G. A., Singer, K. D., Eds.; ACS Symposium Series Vol. 601; American Chemical Society: Washington, DC, 1995. Di Bella, S.; Marks, T. J.; Ratner, M. A. J. Am. Chem. Soc. 1994, 116, 4440. Yu, J.; Zerner, M. C. J. Chem. Phys. 1994, 100, 7487.
    • (1994) J. Chem. Phys. , vol.100 , pp. 7487
    • Yu, J.1    Zerner, M.C.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.