Generation and reactivity of allylic and benzylic samarium compounds using diiodosamarium in tetrahydropyran

Tetrahedron Letters

Volumn 38, Issue 37, 1997, Pages 6585-6588

  Hamann Gaudinet, Béatrice ^a   Namy, Jean Louis ^a   Kagan, Henri B ^a  

^a CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ORGANOMETALLIC COMPOUND; SAMARIUM; TETRAHYDROPYRAN DERIVATIVE;

ARTICLE; CHEMICAL REACTION; REACTION TIME;

EID: 0030750995     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(97)01506-2     Document Type: Article

References (8)

1. Curran, D.P.; Fevig, T.L.; Jasperse, C.P.; Totleben, M.J. Synlett. 1992, 943-961 and references cited therein.
2. Namy, J.-L.; Collin, C.; Bied, C.; Kagan, H.B. Synlett 1992, 733-734.
3. Bied, C.; Collin, J.; Kagan, H.B. Tetrahedron 1992, 48, 3877-3890.
4. Fukuzawa, S.I.; Mutho, K.; Tsuchimoto, T.; Hiyama, T. J. Org. Chem. 1996, 61, 5400-5405.
5. Girard, P.; Namy, J.-L.; Kagan, H.B. J. Am. Chem. Soc. 1980, 102, 2693-2698.
6. Namy, J.-L.; Colomb, M.; Kagan, H.B.; Tetrahedron Lett. 1994, 35, 1723-1726.
7. 2 in THF has been previously observed 3, organoceriums prepared according to Imamoto 8 are also weakly basic.
8. Imamoto, T.; Sugiura, Y.; Takiyama, N. Tetrahedron Lett. 1984, 25, 4233-4236.