Quasi-Complete Solvation of Organic Molecules in the Crystalline State

Angewandte Chemie (International Edition in English)

Volumn 36, Issue 12, 1997, Pages 1301-1303

  Shivanyuk, Alexander ^a   Paulus, Erich F ^b   Böhmer, Volker ^a   Vogt, Walter ^a  

^a JOHANNES GUTENBERG UNIVERSITY   (Germany)

^b SANOFI   (France)

Author keywords

Calixarenes; Hydrogen bonds; Solvation; Supramolecular chemistry

Indexed keywords

EID: 0030750602     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199713011     Document Type: Article

References (28)

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14. 2h symmetrical chair conformation. The rccc isomers having intramolecular cavities were widely used [5] for the complexation of polyols like sugars and steroids through an interplay of cooperative hydrogen bonds and CH-π interactions and for the construction of even more sophisticated receptors such as cavitands, carcerands, and hemicarcerands. However, the rctt isomers have not yet attracted much attention.
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19. 1H NMR spectroscopy, however, the individual compounds were not isolated: F. Weinelt, H.-J. Schneider, J. Org. Chem. 1991, 56, 5527-5535.
20. +].
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25. Anthracene derivatives, bearing two divergent resorcinol residues, have been used to design hydrogen-bonded solid-state networks: Y. Aoyama, K. Endo, T. Anzai, Y. Yamaguchi, T. Sawaki, K. Kobayashi, N. Kanehisa, H. Hashimoto, Y. Kai, H. Masuda, J. Am. Chem. Soc. 1996, 118, 5562-5571.
26. 2) = 0.1675 (for all 6649 unique reflections), S = 1.03, σ(C-C) = 0.003 Å. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-100224. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: int. code +(1223) 336-033; e-mail deposit@chemcrys.cam.ac.uk).
27. 2) = 0.1675 (for all 6649 unique reflections), S = 1.03, σ(C-C) = 0.003 Å. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-100224. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: int. code +(1223) 336-033; e-mail deposit@chemcrys.cam.ac.uk).
28. Only the crystal structure of a completely acylated rctt resorcarene has been described: K. J. Palmer, P. Y. Wong, L. Jurd, K. Stevens, Acta Crystallogr. Sect. B 1976, 32, 847.