Lipase-catalyzed monoesterification of 1-O-Hexadecylglycerol in organic solvents

Lipids

Volumn 32, Issue 8, 1997, Pages 907-911

  Bertello, Laura E ^a   Salto, María Laura ^a   De Lederkremer, Rosa M ^a  

^a UNIVERSIDAD DE BUENOS AIRES   (Argentina)

Author keywords

[No Author keywords available]

Indexed keywords

CHIMYL ALCOHOL; FATTY ACID;

ARTICLE; ESTERIFICATION; NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STRUCTURE ANALYSIS;

CATALYSIS; ESTERIFICATION; FATTY ACIDS; GLYCERIDES; GLYCERYL ETHERS; KINETICS; LIPASE; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR STRUCTURE; PSEUDOMONAS; SOLVENTS; TEMPERATURE;

EID: 0030750149     PISSN: 00244201     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11745-997-0117-x     Document Type: Article

References (20)

1. McConville, M.J., and Ferguson, M.A.J. (1993) The Structure, Biosynthesis and Function of Glycosylated Phosphatidylinositols in the Parasitic Protozoa and Higher Eukaryotes, Biochem. J. 294, 305-324.
2. Lederkremer, R.M., Lima, C.E., Ramirez, M.I., Gonçalvez, M.F., and Colli, W. (1993) Hexadecylpalmitoylglycerol or Ceramide Is Linked to Similar Glycophosphoinositol Anchor-Like Structures in Trypanosoma cruzi, Eur. J. Biochem. 218, 929-936.
3. Heise, N., Cardoso de Almeida, M.L., and Ferguson, M.A.J. (1995) Characterization of the Lipid Moiety of the Glycosylphosphatidylinositol Anchor of Trypanosoma cruzi 1G7-antigen, Molec. Biochem. Parasitol. 70, 71-84.
4. Acosta Serrano, A., Schenkman, S., Yoshida, N., Mehlert, A., Richardson, J.M., and Ferguson, M.A.J. (1995) The Lipid Structure of the Glycosylphosphatidylinositol-Anchored Mucin-Like Sialic Acid Acceptors of Trypanosoma cruzi. Changes During Parasitic Differentiation from Epimastigotes to Infective Metacyclic Trypomastigote Forms, J. Biol. Chem. 270, 27244-27253.
5. Bertello, L.E., Gonçalvez, M.F., Colli, W., and Lederkremer, R.M. (1995) Structural Analysis of Inositol Phospholipids from Trypanosoma cruzi Epimastigote Forms, Biochem. J. 310, 255-261.
6. Uhrig, M.L., Couto, A.S., Colli, W., and Lederkremer, R.M. (1996) Characterization of Inositol Phospholipids in Trypanosoma cruzi Trypomastigote Forms, Biochim. Biophys. Acta. 1300, 233-239.
7. Bornscheuer, U.T. (1995) Lipase-Catalyzed Syntheses of Monoacylglycerols, Enzyme Microb. Technol. 17, 578-586.
8. Kwon, S.J., Han, J.J., and Rhee, J.S. (1995) Production and in situ Separation of Mono- or Diacylglycerol Catalyzed by Lipases in n-Hexane, Enzyme Microb. Technol. 17, 700-704.
9. Meusel, D., Weber, N., and Mukherjee, K.D. (1992) Stereoselectivity of Lipases: Esterification Reactions of Octadecylglycerol, Chem. Phys. Lipids 61, 193-198.
10. Haraldsson, G.G., and Thorarensen, A. (1994) The Generation of Glyceryl Ether Lipids Highly Enriched with Eicosapentaenoic Acid and Docosahexaenoic Acid by Lipase, Tetrahedron Lett. 35, 7681-7684.
11. Virto, M.D., Agud, I., Montero, S. Blanco, A. Solozabal, R., Lascaray, J.M., Llama, M.J., Serra, J.L., Landeta, L.C., and de Renobales, M. (1995) Kinetic Properties of Soluble and Immobilized Candida rugosa Lipase, Appl. Biochem. Biotechnol. 50, 127-136.
12. Sjursnes, B.J., and Anthonsen, T. (1994) Acyl Migration in 1,2-Dibutyrin. Dependence on Solvent and Water Activity, Biocatalysis 9, 285-297.
13. Roberts, W.L., Myher, J.J., Kuksis A., and Rosenberry T.L. (1988) Alkylacylglycerol Molecular Species in the Glycosylinositol Phospholipid Membrane Anchor of Bovine Erythrocyte Acetylcholinesterase, Biochem. Biophys. Res. Commun. 150, 271-277.
14. Gubicza, L., and Szakács-Schmidt, A. (1994) Effects of the Reaction Conditions on the Enantioselective Esterification Using Candida cylindracea Lipase, Biocatalysis 9, 131-143.
15. Miller, C., Austin, H., Posorske, L., and Gonzalez, J. (1988) Characteristic of an Immobilized Lipase for the Commercial Synthesis of Esters, J. Am. Oil Chem. Soc. 65, 927-931.
16. Pastor, E., Otero, C., and Ballesteros, A. (1995) Enzymatic Preparation of Mono- and Di-Stearin by Glycerolysis of Ethyl Stearate and Direct Esterification of Glycerol in the Presence of a Lipase from Candida antarctica (Novozym 435), Biocatal. Biotransform. 12, 147-157.
17. Chaudhary, S.K., and Hernandez, O. (1979) A Simplified Procedure for the Preparation of Triphenylmethylethers, Tetrahedron Lett. 2, 95-98.
18. Hassner, A., and Alexanian, V. (1978). Direct Room Temperature Esterification of Carboxylic Acids, Tetrahedron Lett. 46, 4475-4478.
19. 3Na-(1-6)-α-Glc-(1-6)-α-Glc-(1-3)]-sn-glycerol: A Proposed Structure for the Glyceroglucolipids of Human Gastric Secretion and of the Mucous Barrier of Rat-Stomach Antrum, Carbohydr. Res. 123, C1-C4.
20. Subrahmanyam, C., Venkateswara Rao, C., Anjaneyulu, V., Satyanarayana, P., Subba Rao, P.V., Ward, R.S., and Pelter, A. (1992) New Diterpenes from a New Species of Lobophytum Soft Coral of the South Andaman Coast, Tetrahedron 48, 3111-3120.