Gas-phase chemistry of methyl(trimethylsilyl)germylene

Tetrahedron

Volumn 53, Issue 29, 1997, Pages 10179-10196

  Lei, Deqing ^a   Lee, Myong Euy ^a   Gaspar, Peter P ^a  

^a WASHINGTON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ORGANOGERMANIUM COMPOUND; ORGANOSILICON DERIVATIVE;

ARTICLE; DRUG STRUCTURE; GAS CHROMATOGRAPHY; MOLECULAR DYNAMICS; PRIORITY JOURNAL; PYROLYSIS; TEMPERATURE;

EID: 0030747639     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(97)00385-2     Document Type: Article

References (13)

1. For a recent review of germylene chemistry, see: Neumann, W.; Chem. Revs., 1991, 91, 311.
2. Wulff, W.D.; Goure, W.F.; Barton, T.J.; J. Am. Chem. Soc., 1978, 100, 6236.
3. Davidson, I.M.T.; Scampton, R.J. J. Organometal. Chem. 1984, 271, 249.
4. Boo, B.H.; Gaspar, P.P. Organometallics, 1986, 5, 698.
5. Lee, M.E.; North, M.A.; Gaspar, P.P. Phosphorus, Sulfur, and Silicon, 1991, 56, 203.
6. 3: Baines, K.M.; Cooke, J.A.; Organometallics, 1992, 11, 3487.
7. Bobbitt, K.L.; Maloney, V.M.; Gaspar, P.P. Organometallics, 1991, 10, 2772.
8. Atwell, W.H.; Weyenberg, D.R.; J. Am. Chem. Soc., 1968, 90, 3438.
9. Wiberg, N.; Preiner, G.; Schiede, O.; Fischer, G. Chem. Ber.,1981, 114, 3505.
10. For the analogous silylsilylene 1 strain energy would have to be added to the ca. 15 kcal/mol. barrier associated with insertion into a C-H bond to give an estimated barrier for formation of the disilirane ring 2 of >20 kcal/mol.
11. Neumann, W.P.; Michels, E.; Kocher, T. Tetrahedron Lett., 1987, 28, 3783.
12. Lee, M. E.; Bobbitt, K. L.; Lei, D.; Gaspar, P. P. Synth. React. Inorg. Met.-Org. Chem. 1990, 20, 77.
13. Boo, B. H.; Gaspar, P. P. Organometallics, 1986, 5, 698.