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85033175745
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note
-
T should be depleted at the present excitation wavelength (701 nm). where the absorptuion of P700 is dominant. It is thus assumed that the present time-resolved fluorescence results mostly from the RCs which are in the ground state before excitation.
-
-
-
-
42
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85033186554
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-
note
-
Curve fitting of three-exponential functions with two fixed time constants of 1 and 12-14 ps to the parallel and perpendicular data in the time region between -0.25 and 0.5 ps did not converge properly.
-
-
-
-
43
-
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85033182575
-
-
note
-
- should not depend on the polarization conditions.
-
-
-
-
44
-
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85033173183
-
-
note
-
There remains a residual equilibration process even after 3 ps, as indicated by the slow anisotropy change with ≈10-ps time constant. Its contribution to the anisotropy change is at most ≈0.05. We regard that the ≈1-ps equilibration process achieves full equilibration of the excited states for simplicity in the following discussion.
-
-
-
-
47
-
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85033184448
-
-
note
-
P700 is assumed to be about half that estimated in ref 11.
-
-
-
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48
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84984240011
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49049141536
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51
-
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85033187890
-
-
note
-
This set of spectral decomposition data was obtained by Prof. S. Itoh. Prof. M. Mimura, and Dr. M. Iwaki and used here with their permission. See also ref 36.
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