메뉴 건너뛰기




Volumn 53, Issue 52, 1997, Pages 17761-17768

Halogen atom transfer radical addition of α-polychloroesters to olefins promoted by Fe0 filings

Author keywords

[No Author keywords available]

Indexed keywords

2,2 DICHLOROCARBOXYLATE; ALKENE; BUTYROLACTONE; HALIDE; IRON; TRICHLOROACETIC ACID; UNCLASSIFIED DRUG;

EID: 0030724226     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(97)10241-1     Document Type: Article
Times cited : (43)

References (52)
  • 6
    • 4243922925 scopus 로고
    • Georg Thieme Verlag: Stuttgart
    • (c) Giese, B.; Ghosez, A.; Zipse, H. in Houben-Weil, Georg Thieme Verlag: Stuttgart, 1989, vol. E19a/2, 876 ff.
    • (1989) Houben-Weil , vol.E19A-2
    • Giese, B.1    Ghosez, A.2    Zipse, H.3
  • 21
    • 0343159277 scopus 로고    scopus 로고
    • Japan Kokai 77,133,908
    • (e) Yusuke, I.; Masato, O. Japan Kokai 77,133,908 (C. A. 1978, 88, 152013m);
    • Yusuke, I.1    Masato, O.2
  • 22
    • 24444468116 scopus 로고
    • (e) Yusuke, I.; Masato, O. Japan Kokai 77,133,908 (C. A. 1978, 88, 152013m);
    • (1978) C. A. , vol.88
  • 24
    • 25544453215 scopus 로고
    • (f) Karapet'yan, Sh. A.; Belyavskii, A.B.; Kuz'mina, N.A. Izv. Akad. Nauk SSSr, Ser. Khim., 1973, 6, 1272 (C.A. 1973, 79, 91497n);
    • (1973) C.A. , vol.79
  • 25
    • 0343594720 scopus 로고    scopus 로고
    • Eur. Pat. Appl. Ep. 131, 561
    • (g) Santford, W.S.; Eur. Pat. Appl. Ep. 131, 561 (C. A. 1973, 103, 53693a);
    • Santford, W.S.1
  • 26
    • 24444471064 scopus 로고
    • (g) Santford, W.S.; Eur. Pat. Appl. Ep. 131, 561 (C. A. 1973, 103, 53693a);
    • (1973) C. A. , vol.103
  • 27
    • 0342724771 scopus 로고    scopus 로고
    • (h) Hoechst, Brit. 803, 463 (C. A. 1959, 53, 11222b).
    • Brit. , vol.803 , pp. 463
    • Hoechst1
  • 28
    • 24444455438 scopus 로고
    • (h) Hoechst, Brit. 803, 463 (C. A. 1959, 53, 11222b).
    • (1959) C. A. , vol.53
  • 34
    • 0342724768 scopus 로고    scopus 로고
    • Other metals have been tested, but with very poor results
    • Other metals have been tested, but with very poor results.
  • 35
    • 0342724769 scopus 로고    scopus 로고
    • Both in DCE or PE alone the reaction does not proceed
    • Both in DCE or PE alone the reaction does not proceed.
  • 36
    • 0343159275 scopus 로고    scopus 로고
    • note
    • The addition into the reaction mixture of ligands like dipyridyl, pyridine, triphenylphosphine does not produce any sort of improvment; furthermore, when these ligands are used in solvents other than DMF, no reaction was observed.
  • 44
    • 0343594718 scopus 로고    scopus 로고
    • The C-C triple bond was completely unreactive; furthermore, the observed low ester conversion suggest a some sort of inhibiting action
    • The C-C triple bond was completely unreactive; furthermore, the observed low ester conversion suggest a some sort of inhibiting action.
  • 51
    • 0343594715 scopus 로고    scopus 로고
    • note
    • The volume of the reaction mixture greatly affects the yields of the reactions. In fact, high headspace negatively affect the reaction, owing to the partition of olefin and dichloroester between liquid and vapour phase; the best yields are obtained on working with Schlenk capacity little higher than the reaction volume. In this condition the amount of solvent can be drastically reduced.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.