Building off the back of chelators: Synthesis of 3,3''-bis(4- methylphenyl)-2,2':6',2''-terpyridine

Tetrahedron Letters

Volumn 38, Issue 47, 1997, Pages 8279-8282

  Benniston, Andrew C ^a  

^a UNIVERSITY OF GLASGOW   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

CHELATING AGENT; LIGAND; MACROCYCLIC COMPOUND; PYRIDINE DERIVATIVE;

ARTICLE; CHEMICAL REACTION; COMPLEX FORMATION; CRYSTALLIZATION; HYDROLYSIS; SYNTHESIS; THERMODYNAMICS; TRANS ISOMER;

EID: 0030719399     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(97)10167-8     Document Type: Article

References (20)

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3. M. Beley, S. Chodorowski-Kimmes, J-P. Collin, P. Lainé, J-P. Launay, J-P. Sauvage, Angew. Chem., Int. Ed. Engl. 1994, 33, 1775-1778.
4. F. Kröhnke, Synthesis, 1976, 1-24.
5. K. T. Potts, M. J. Cipullo, P. Ralli, G. Theodoridis, J. Org. Chem. 1982, 47, 3027-3038.
6. D. L. Jameson, L. E. Guise, Tetrahedron Lett. 1991, 32, 1999-2002.
7. A detailed search of the Beilsteín database found only one other 3,3"-derivatised terpy ligand, see: M. Tingoli, M. Tiecco, L. Testaferri, R. Andrenacci, R. Balducci, J. Org. Chem. 1993, 58, 6097-6102.
8. A. C. Benniston, P. R. Mackie, A. Harriman Tetrahedron Lett. 1997, 38, 3577-3580.
9. J-P. Sauvage, M. Ward, Inorg. Chem. 1991, 30, 3869-3874.
10. +.
11. 3, 200MHz); δ = 2.36 (s, 3H); 7.23-7.27 (d, 2H, J= 8.0Hz); 7.37-7.41 (d, 2H, J= 8.0Hz); 7.28-7.32 (d, 1H, J= 7.3Hz); 7-37-7.45 (t, 1H, J= 7.2Hz); 8.12-8.15 (d, 1H, J= 6.3Hz); 8.40(s, 1H).
12. +.
13. +
14. +.
15. E. Constable, M. Ward, S. Corr, Inorg. Chim. Acta. 1988, 141, 201-203.
16. +.
17. 2O %C 53.61, %H 4.66, %N 6.47 found: %C 53.84, %H 4.06, %N 6.65.
18. E. C. Constable Adv. Inor.Chem. Radiochem. 1986, 30 69-121.
19. +.
20. A. C. Benniston, A. Harriman, J. Am. Chem. Soc. 1994, 116, 11531-11537.