Critical discussion of simple adsorption methods used to evaluate the micropore size distribution

Adsorption

Volumn 3, Issue 3, 1997, Pages 209-219

  Kruk, Michal ^a   Jaroniec, Mietek ^a   Choma, Jerzy ^b  

^a KENT STATE UNIVERSITY   (United States)

^b MILITARY UNIVERSITY OF TECHNOLOGY   (Poland)

Author keywords

Carbons; Dubinin Astakhov equation; Gas adsorption; Horvath Kawazoe method; Porous structure

Indexed keywords

ADSORPTION ISOTHERMS; GRAPHITE; MATHEMATICAL MODELS; MONOLAYERS; POROSITY; POROUS MATERIALS;

DENSITY FUNCTIONAL THEORY (DFT); DUBININ-ASTAKHOV (DA) EQUATION; HORVATH-KAWAZOE (HK) METHOD;

GAS ADSORPTION;

EID: 0030717803     PISSN: 09295607     EISSN: None     Source Type: Journal    
DOI: 10.1007/BF01650132     Document Type: Review

References (24)

1. Advanced Zeolite Science and Applications, J.C. Jansen, M. Stocker, H.G. Karge and J. Weitkamp (Eds.), Studies in Surface Science and Catalysis, 85, Elsevier, Amsterdam and New York, 1994.
2. Bansal, R.C., J.-B. Donnet, and F. Stoeckli, Active Carbon, Marcel Decker, Inc., New York and Basel, 1988.
3. Bereznitski, Y., M. Jaroniec, and K.P. Gadkaree, "Influence of Analysis Conditions on Low Pressure Adsorption Measurements and its Consequences in Characterization of Energetic and Structural Heterogeneity of Microporous Carbons," Adsorption (1997), (in press).
4. Characterization and Modification of the Silica Surface, E.F. Vansant, P. Van der Voort, and K.C. Vrancken (Eds.), Elsevier, Amsterdam, 1995.
5. Cheng, L.S. and R.T. Yang, "Improved Horvath-Kawazoe Equations Including Spherical Pore Models for Calculating Micropore Size Distribution," Chem. Eng. Sci., 49, 2599-2609 (1994).
6. Chmiel, G., L. Lajtar, S. Sokolowski, and A. Patrykiejew, "Adsorption in Energetically Heterogeneous Slit-like Pores: Comparison of Density Functional Theory and Computer Simulations," J. Chem. Soc. Faraday Trans., 90, 1153-1156 (1994).
7. Choma, J., M. Jaroniec, and J. Klinik, "Micropore Size Distribution Functions for Active Carbons Calculated from Low Temperature Nitrogen Adsorption," Karbo-Energochemia-Ekologia, 10, 258 (1994).
8. Dubinin, M.M., "Physical Adsorption of Gases and Vapors in Micropores," Progress Surface Membrane Sci., 9, 1-69 (1975).
9. Horvath, G. and K. Kawazoe, "Method for Calculation of Effective Pore Size Distribution in Molecular Sieve Carbon," J. Chem. Eng. Japan, 16, 470-475 (1983).
10. Jaroniec, M., "Thermodynamics of Gas Adsorption on Heterogeneous Microporous Solids," Langmuir, 3, 795-799 (1987).
11. Jaroniec, M., "Characterization of Nanoporous Materials," Access to Nanoporous Materials, T.J. Pinnavaia and M. Thorpe (Eds.), pp. 255-272, Plenum Press, New York, 1996.
12. Jaroniec, M. and R. Madey, Physical Adsorption on Heterogeneous Surfaces, Elsevier, Amsterdam, 1988.
13. Jaroniec, M., K.P. Gadkaree, and J. Choma, "Relation Between Adsorption Potential Distribution and Pore Volume Distribution for Microporous Carbons," Colloids and Surfaces, 118, 203-210 (1996).
14. Kaminsky, R.D., E. Maglara, and W.C. Connor, "A Direct Assessment of Mean-Field Methods of Determining Pore Size Distributions of Porous Media from Adsorption Isotherm Data," Langmuir, 10, 1556-1565 (1994).
15. Karykowski, K., W. Rzysko, A. Patrykiejew, and S. Sokolowski, "Grand Canonical Ensemble Monte Carlo Simulations of Adsorption in Energetically Heterogeneous Slit-like Pores," Thin Solid Films, 249, 236-240 (1994).
16. Kresge, C.T., M.E. Leonowicz, W.J. Roth, J.C. Vartuli, and J.S. Beck, "Ordered Mesoporous Molecular Sieves Synthesized by a Liquid-Crystal Template Mechanism," Nature, 359, 710-712 (1992).
17. Kruk, M., M. Jaroniec, and Y. Bereznitski, "Adsorption Study of Porous Structure Development in Carbon Blacks," accepted to J. Col. Surf. Sci., (1996).
18. Lastoskie, C., K.E. Gubbins, and N. Quirke, "Pore Size Distribution Analysis of Microporous Carbons: A Density Functional Theory Approach," J. Phys. Chem., 97, 4786-4796 (1993a).
19. Lastoskie, C., K.E. Gubbins, and N. Quirke, "Pore Size Heterogeneity and the Carbon Slit Pore: A Density Functional Theory Model," Langmuir, 9, 3693-3702 (1993b).
20. Olivier, J.P., "Modeling Physical Adsorption on Porous and Nonporous Solids Using Density Functional Theory," J. Porous Mater., 2, 9-17 (1995).
21. Olivier, J.P., W.B. Conklin, and M.v. Szombathely, "Determination of Pore Size Distribution from Density Functional Theory: A Comparison of Nitrogen and Argon Results," Stud. Surf. Sci. Catal., 87, 81-89 (1994).
22. Szombathely, M., M. Brauer, and M. Jaroniec, "The Solution of the Adsorption Integral Equations by Means of the Regularization Method," J. Comput. Chem., 13, 17-32 (1992).
23. The Colloid Chemistry of Silica, H.E. Bergna (Ed.), Amer. Chem. Soc., Washington, D.C., (1994).
24. Zeolites: A Refined Tool for Designing Catalytic Sites, L. Bonneviot and S. Kaliaguine (Eds.), Studies in Surface Science and Catalysis, 97, Elsevier, New York, 1995.