Center-propagating type polymerization of thiirane using an acyl-group transfer polymerization

Polymer Journal

Volumn 29, Issue 6, 1997, Pages 550-552

  Kawakami, Susumu ^a   Kameyama, Atsushi ^a   Miyata, Mitsuhiro ^a   Nishikubo, Tadatomi ^a  

^a KANAGAWA UNIVERSITY   (Japan)

Author keywords

Center Propagating Type Polymerization; Group Transfer Polymerization; S Thioesters; Thiirane

Indexed keywords

COMPOSITION EFFECTS; INITIATORS (CHEMICAL); MOLECULAR STRUCTURE; MOLECULAR WEIGHT; MONOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERIZATION; SYNTHESIS (CHEMICAL);

BIFUNCTIONAL INITIATOR; CENTER PROPAGATING POLYMERIZATION; PHENOXYPROPYLENE SULFIDE; THIIRANE;

AROMATIC POLYMERS;

EID: 0030710301     PISSN: 00323896     EISSN: None     Source Type: Journal    
DOI: 10.1295/polymj.29.550     Document Type: Article

References (5)

1. H. R. Kricheldorf, S. R. Lee, and N. Scharnagl, Macromolecules, 27, 3139 (1994).
2. a) A. Kameyama, K. Shimotsuma, and T. Nishikubo, Macromol. Rapid Commun., 15, 335 (1994).
3. b) A. Kameyama, K. Shimotsuma, and T. Nishikubo, Polym. J., 28, 66 (1996).
4. 3/methanol and then collected by decantation and dried under reduced pressure to give final product. Yield=0.767 g (94%). The polymer yield was calculated by the following equation, Yield (%)=[W/(I+T)]×100, in which W is weight of the obtained polymer, I and T are weights of the initiator and the used thiirane monomer, respectively.
5. 2-OPh), 6.82-7.19 (m, 5.4H, aromatic H), 7.85-7.92 (m, 0.2H, aromatic H).