Synthesis of a Triiodide-Like Pentamesityltritellurium Cation by Addition of Dimesityltelluride to the Remarkably Electrophilic Trimesitylditelluronium Ion

Angewandte Chemie (International Edition in English)

Volumn 36, Issue 20, 1997, Pages 2219-2221

  Jeske, Jörg ^a   Du Mont, Wolf Walther ^a   Jones, Peter G ^a  

^a Inst Anorganische Analyt Chem T   (Germany)

Author keywords

Cations; Chalcogens; Hypervalent compounds; Tellurium

Indexed keywords

EID: 0030693119     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199722191     Document Type: Article

References (27)

1. P. Böttcher, Angew. Chem. 1988, 100, 781-794; Angew. Chem Int. Ed. Engl. 1988, 27, 759-772.
2. P. Böttcher, Angew. Chem. 1988, 100, 781-794; Angew. Chem Int. Ed. Engl. 1988, 27, 759-772.
3. D. Y. Valentine, O. B. Cavin, H. L. Yakel, Acta Crystallogr. Sect. B. 1977, 33, 1389-1396.
4. M. G. Kanatzidis, Angew. Chem. 1995, 107, 2281-2283, Angew. Chem. Int. Ed. Engl. 1995, 34, 2109-2111.
5. M. G. Kanatzidis, Angew. Chem. 1995, 107, 2281-2283, Angew. Chem. Int. Ed. Engl. 1995, 34, 2109-2111.
6. a) U. Müller C. Grebe, B. Neumüller, B. Schreiner, K. Dehnicke, Z. Anorg. Allg. Chem. 1993, 619, 500-506;
7. b) B. Schreiner, K. Dehnicke, K. Maczek, D. Fenske, ibid. 1993, 619, 1414-1418.
8. a) M. A. Ansari, J. C. Bollinger, J. A. Ibers, Inorg. Chem. 1993, 32, 23-232;
9. b) D. M. Smith, L. C. Roof, M. A. Ansari, J. M. McConnachie, J. C. Bollinger, M. A. Pell, R. J. Salm, J. A. Ibers, ibid. 1996, 35, 4999-5006.
10. W. S. Sheldrick, M. Wachold, Angew. Chem. 1995, 107, 490-492; Angew. Chem. Int. Ed. Engl. 1995, 34, 450-451.
11. W. S. Sheldrick, M. Wachold, Angew. Chem. 1995, 107, 490-492; Angew. Chem. Int. Ed. Engl. 1995, 34, 450-451.
12. Q. Liu, N. Goldberg, R. Hoffmann, Chem. Eur. J. 1996, 2, 390-397.
13. W. -W. du Mont, J. Jeske, P. G. Jones. Angew. Chem. 1996, 108, 2822-2824; Angew. Chem. Int. Ed. Engl. 1996, 35, 2653-2655.
14. W. -W. du Mont, J. Jeske, P. G. Jones. Angew. Chem. 1996, 108, 2822-2824; Angew. Chem. Int. Ed. Engl. 1996, 35, 2653-2655.
15. T. P. Hilditch, S. Smiles, J. Chem. Soc. 1907, 91, 1394-1399; D. J. Pettit, G. K. Helmkamp, J. Org. Chem. 1963, 28, 2932-2933.
16. T. P. Hilditch, S. Smiles, J. Chem. Soc. 1907, 91, 1394-1399; D. J. Pettit, G. K. Helmkamp, J. Org. Chem. 1963, 28, 2932-2933.
17. a) G. Capozzi, O. De Lucchi, V. Lucchini, G. Modena, Synthesis 1976, 677-678;
18. b) B. M. Trost, T. Shibata, J. Am. Chem. Soc. 1982, 104, 3225-3228 and references therein.
19. R. Laitinen, R. Steudel, R. Weiss, J. Chem Soc. Dalton Trans. 1986, 1095-1100; R. Minkwitz, H. Prenzel, H. Pritzkow, Z. Naturforsch. B 1987, 42, 750-755.
20. R. Laitinen, R. Steudel, R. Weiss, J. Chem Soc. Dalton Trans. 1986, 1095-1100; R. Minkwitz, H. Prenzel, H. Pritzkow, Z. Naturforsch. B 1987, 42, 750-755.
21. -3. The relatively high residual value results from the disordered dichloromethane molecules. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-100-165. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: int. code +(1223) 336-033; e-mail: deposit@chemcrys.cam.ac.uk).
22. A. Edelmann, S. Brooker, N. Bertel, M. Noltemeyer, H. W. Roesky, G. M. Sheldrick, F. T. Edelmann, Z. Naturforsch. B 1992, 47, 305-309.
23. "10-Te-4" denotes 10 valence electrons around the central Te atom, to which four substituent, are attached: C. W. Perkins, J. C. Martin, A. J. Arduengo III., W. Lau, A. Alegria, J. K. Kochi, J. Amer. Chem. Soc. 1980, 102, 7753-7759.
24. M. Bätcher, W.-W. du Mont, S. Pohl, W. Saak, Phosphorus, Sulfur Silicon Relat. Elem. 1990, 49/50, 147-150.
25. S. Hauge, O. Vikane, Acta Chem. Scand. Ser A 1983, 37, 723-729.
26. W.-W. du Mont, H. -H. Meyer, S. Kubiniok, S. Pohl, W. Saak, Chem. Ber. 1992, 125, 761-766.
27. P. Böttcher, R. Keller, J. Less-Common Met. 1985, 109, 311-321.