General expression for rates of solution reactions influenced by slow solvent fluctuations, and its experimental evidence

Electrochimica Acta

Volumn 42, Issue 18, 1997, Pages 2763-2777

  Sumi, Hitoshi ^a   Asano, Tsutomu ^b,c  

^a UNIVERSITY OF TSUKUBA   (Japan)

^b OITA UNIVERSITY   (Japan)

^c KYUSHU UNIVERSITY   (Japan)

Author keywords

Kramers theory; Non TST regime; Solvent fluctuation; Thermalization time; Viscosity

Indexed keywords

CONFORMATIONS; DIFFUSION IN LIQUIDS; ISOMERIZATION; MATHEMATICAL MODELS; MOLECULAR ORIENTATION; MOLECULAR STRUCTURE; MOLECULAR VIBRATIONS; RELAXATION PROCESSES; SOLVENTS; THERMAL EFFECTS; VISCOSITY OF LIQUIDS;

KRAMERS THEORY; SOLVENT FLUCTUATION; THERMALIZATION TIME; TRANSITION STATE THEORY;

REACTION KINETICS;

EID: 0030675727     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0013-4686(97)00080-7     Document Type: Article

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75. D. H. Waldeck, W. T. Lotshaw, D. B. McDonald and G. R. Fleming, Chem. Phys. Lett. 88, 297 (1982); M. van der Auveraer, M. van den Zegel, N. Boens, F. C. de Schryver and F. Willig, J. Phys. Chem. 90, 1169 (1986); M. Lee, A. J. Bain, P. J. McCarthy, C. H. Han, J. N. Haseltine, A. B. Smith III and R. M. Hochstrasser, J. Chem. Phys. 85, 4341 (1986); A. Ansari, C. M. Jones, E. R. Henry, J. Hofrichter and W. A. Eaton, Science 256, 1796 (1992); E. Laitinen, P. Ruuskanen-Järvinen, U. Rempel, V. Helenius and J. E. I. Korppi-Tommola, Chem. Phys. Lett. 218, 73; (1994) and W. Mikosch, Th. Dormfüller and W. Eimer, J. Chem. Phys. 101, 11044 (1994).
76. D. H. Waldeck, W. T. Lotshaw, D. B. McDonald and G. R. Fleming, Chem. Phys. Lett. 88, 297 (1982); M. van der Auveraer, M. van den Zegel, N. Boens, F. C. de Schryver and F. Willig, J. Phys. Chem. 90, 1169 (1986); M. Lee, A. J. Bain, P. J. McCarthy, C. H. Han, J. N. Haseltine, A. B. Smith III and R. M. Hochstrasser, J. Chem. Phys. 85, 4341 (1986); A. Ansari, C. M. Jones, E. R. Henry, J. Hofrichter and W. A. Eaton, Science 256, 1796 (1992); E. Laitinen, P. Ruuskanen-Järvinen, U. Rempel, V. Helenius and J. E. I. Korppi-Tommola, Chem. Phys. Lett. 218, 73; (1994) and W. Mikosch, Th. Dormfüller and W. Eimer, J. Chem. Phys. 101, 11044 (1994).
77. D. H. Waldeck, W. T. Lotshaw, D. B. McDonald and G. R. Fleming, Chem. Phys. Lett. 88, 297 (1982); M. van der Auveraer, M. van den Zegel, N. Boens, F. C. de Schryver and F. Willig, J. Phys. Chem. 90, 1169 (1986); M. Lee, A. J. Bain, P. J. McCarthy, C. H. Han, J. N. Haseltine, A. B. Smith III and R. M. Hochstrasser, J. Chem. Phys. 85, 4341 (1986); A. Ansari, C. M. Jones, E. R. Henry, J. Hofrichter and W. A. Eaton, Science 256, 1796 (1992); E. Laitinen, P. Ruuskanen-Järvinen, U. Rempel, V. Helenius and J. E. I. Korppi-Tommola, Chem. Phys. Lett. 218, 73; (1994) and W. Mikosch, Th. Dormfüller and W. Eimer, J. Chem. Phys. 101, 11044 (1994).
78. D. H. Waldeck, W. T. Lotshaw, D. B. McDonald and G. R. Fleming, Chem. Phys. Lett. 88, 297 (1982); M. van der Auveraer, M. van den Zegel, N. Boens, F. C. de Schryver and F. Willig, J. Phys. Chem. 90, 1169 (1986); M. Lee, A. J. Bain, P. J. McCarthy, C. H. Han, J. N. Haseltine, A. B. Smith III and R. M. Hochstrasser, J. Chem. Phys. 85, 4341 (1986); A. Ansari, C. M. Jones, E. R. Henry, J. Hofrichter and W. A. Eaton, Science 256, 1796 (1992); E. Laitinen, P. Ruuskanen-Järvinen, U. Rempel, V. Helenius and J. E. I. Korppi-Tommola, Chem. Phys. Lett. 218, 73; (1994) and W. Mikosch, Th. Dormfüller and W. Eimer, J. Chem. Phys. 101, 11044 (1994).
79. D. H. Waldeck, W. T. Lotshaw, D. B. McDonald and G. R. Fleming, Chem. Phys. Lett. 88, 297 (1982); M. van der Auveraer, M. van den Zegel, N. Boens, F. C. de Schryver and F. Willig, J. Phys. Chem. 90, 1169 (1986); M. Lee, A. J. Bain, P. J. McCarthy, C. H. Han, J. N. Haseltine, A. B. Smith III and R. M. Hochstrasser, J. Chem. Phys. 85, 4341 (1986); A. Ansari, C. M. Jones, E. R. Henry, J. Hofrichter and W. A. Eaton, Science 256, 1796 (1992); E. Laitinen, P. Ruuskanen-Järvinen, U. Rempel, V. Helenius and J. E. I. Korppi-Tommola, Chem. Phys. Lett. 218, 73; (1994) and W. Mikosch, Th. Dormfüller and W. Eimer, J. Chem. Phys. 101, 11044 (1994).
80. D. H. Waldeck, W. T. Lotshaw, D. B. McDonald and G. R. Fleming, Chem. Phys. Lett. 88, 297 (1982); M. van der Auveraer, M. van den Zegel, N. Boens, F. C. de Schryver and F. Willig, J. Phys. Chem. 90, 1169 (1986); M. Lee, A. J. Bain, P. J. McCarthy, C. H. Han, J. N. Haseltine, A. B. Smith III and R. M. Hochstrasser, J. Chem. Phys. 85, 4341 (1986); A. Ansari, C. M. Jones, E. R. Henry, J. Hofrichter and W. A. Eaton, Science 256, 1796 (1992); E. Laitinen, P. Ruuskanen-Järvinen, U. Rempel, V. Helenius and J. E. I. Korppi-Tommola, Chem. Phys. Lett. 218, 73; (1994) and W. Mikosch, Th. Dormfüller and W. Eimer, J. Chem. Phys. 101, 11044 (1994).